We describe the first use of Bis-tris propane {2,2'-(propane-1,3-diyldiimino)bis[2-(hydroxymethyl)propane-1,3-diol], H(6)L}, in nickel and cobalt chemistry and report the synthesis, structure and magnetic properties of [Ni(4)(H(4)L)(H(3)L)(acac)(2)](+) (1) and [Co(II)(3)Co(III)(2)(H(2)L)(2)(acac)(3)(MeOH)](+) (2).

Six novel copper(ii) complexes of [CuCl]ClO4 (), [Cu(acac)]PF6 (), [CuCl]2(PF6)2 (), [CuCl]2(PF6)2 (), [Cu(acac)]PF6 () and [Cu(acac)]PF6 (), ( = 1-naphthyl-N,N-[bis(2-pyridyl)methyl]amine, = R/S-1-naphthyl-N,N-[bis(2-pyridyl)methyl]ethanamine, acac = diacetone) were synthesized to serve as artificial nucleases. All complexes were structurally characterized using X-ray crystallography. The crys...

Volatile trends are established for a series of M(b-diketonate)n complexes, where M = Cu (n = 2); Al, Sc, Cr, Fe, Co, Ga (n = 3); Zr (n = 4) and b-diketonate = acetylacetonate (acac), trifluoroacetylacetonate (tfac), hexafluoroacetylacetonate (hfac) and 2,2,6,6-tetramethyl-3,5-heptanedionate (tmhd). Sublimation enthalpies (DHsub) were calculated from thermogravimetric analysis (TGA) data, which...

A novel series of mixed-valent, heteroleptic transition metal diketonates that can be utilized as prospective single-source precursors for the low-temperature preparation of oxide materials are reported. The first mixed-valent iron β-diketonates with different FeIII/FeII ratios have been synthesized by applying the mixed-ligand approach. Based on nearly quantitative reaction yields and analysis...

Werndrup, Pia. 2005. Synthesis, Structure Determination, and Sol-Gel Processing of Heterometallic Heteroleptic Alkoxide Complexes of Late Transition Metals. Doctor’s dissertation. ISSN 1652-6880, ISBN 91-576-7026-9. The thesis describes synthesis of single-source precursors (SSP) for sol-gel preparation of thin films and nanocomposites. The structures of the SSPs were determined by singlecrysta...

Background: Olive mill wastewater (OMW) is characterized by its high organic content and refractory compounds. The aim of this study was to evaluate compare the efficiency UV/O3 UV/ acetylacetone (UV/AcAc) processes for treatment pretreated OMW coagulation/microfiltration (C&M) process. Methods: In study, a laboratory-scale UV plug flow reactor with ancillary equipment fabricated. experimen...

We have developed a new class of MRI contrast agents that contain VO-chelated organic ligands, namely VO(acac)2. As contrast agents, vanadyl (VO ) chelates provided excellent T1 and T2 * contrasts compared to that of GdDTPA in high-resolution MR images of rodent tumors. This class of contrast agents is taken up by cancer cells that are highly glycolytic. In vivo MRI experiments demonstrated pre...

We report a simple, yet general, approach to monodisperse MPt (M = Fe, Co, Ni, Cu, Zn) nanoparticles (NPs) by coreduction of M(acac)2 and Pt(acac)2 (acac = acetylacetonate) with oleylamine at 300 °C. In the current reaction condition, oleylamine serves as the reducing agent, surfactant, and solvent. As an example, we describe in details the synthesis of 9.5 nm CoPt NPs with their compositions c...

The nitrosation of acetylacetone (AcAc) has been revised in an aqueous acid medium of perchloric acid and buffers of mono-, di-, or tri-chloroacetic acid. The results show that in the presence of buffers, under conditions of [nit] ≪ [AcAc] (nit = sodium nitrite) the reaction cannot be studied by UV-Vis spectroscopy, contrary to the recently published paper by García-Rio et al. (J. Org. Chem., 2...

In the fourth sentence of the second paragraph under the subheading “[Pt(acac)2(DMS)] decreases expression and activity of MMP-2 and -9” in the Results section, the units for SB203580 should be listed in μM instead of mM. The correct sentence is: When SH-SY5Y cells were pretreated for 30 min with SB203580 (1 and 10 μM), and then with 0.50 μM [Pt(acac)2(DMS)] for 24 h, the inhibition of MMP-2 an...