CeO2 and Y2O3-stabilized zirconia (YSZ) are two typical candidates for electrolyte materials in solid oxide fuel cells attributed to their high ion conductivities. However, the conductivities of these materials are closely connected with high temperatures. Therefore, it is important to develop electrolyte materials which can conduct oxygen ions at lower temperatures. Recent experiments have sho...

Nanocrystalline partially stabilised zirconia (PSZ) and yttria-fully stabilised zirconia (YSZ) powders were prepared by solution combustion process. Nanocrystalline nature of the powders was confirmed by XRD and TEM. Nanocomposite Ni/PSZ and Ni/YSZ films were electrodeposited from a suspension of nanoparticles in nickel sulfamate solution. The strengthening of the nanocomposite due to nanoparti...

The shortcomings at elevated operation temperatures of the standard material yttria-stabilized zirconia (YSZ) for thermal barrier coatings (TBCs) have initiated many research activities seeking alternatives. One candidate is the pyrochlore lanthanum zirconate La2Zr2O7 (LZ), which is phase-stable to its melting point. At the same time, it shows a lower thermal conductivity and a lower sintering ...

In this paper, the formation of ZrO₂ and yttria-stabilised-zirconia (YSZ) aqueous colloidal systems via microwave assisted hydrothermal synthesis is studied. Microwave synthesis allows a fast screening of the influence of different parameters such as time and temperature. The temperature varied from 140 °C up to 180 °C and the used reaction time varied from 5 min up to 1 h. The synthesised zirc...

Cu-based, solid oxide fuel cell (SOFC) electrodes were modified by electrodeposition of Co. The addition of only 5-vol% Co by electrodeposition significantly improved the thermal stability compared to either Cu-ceriaYSZ, Cu-Co-ceria-YSZ, or Co-ceria-YSZ electrodes prepared only by impregnation with much higher metal loadings, demonstrating that electrodeposited metal layers form metal films wit...

Thermal barrier coatings (TBCs) based on Yttria-stabilized Zirconia (YSZ) deposited by the solution precursor plasma spray (SPPS) technique have been claimed to exhibit superior durability compared to conventional plasma spraying and even electron-beam physical vapor deposition. This has been attributed to the interesting features, like vertical cracks, nanosized pores, and fine splats that are...

This paper describes the fabrication and investigation of morphologically stable model electrode structures with well-defined and sharp platinum/yttria-stabilized zirconia YSZ interfaces to study geometric effects at triple phase boundaries TPBs . A nanosphere patterning technique using monodispersed silica nanoparticles, which are applied to the YSZ surface by the Langmuir– Blodgett method, is...

The YSZ-NiO ceramics for solid oxide fuel cells (SOFCs) anode have been investigated. A series of specimens were singly reduced in a hydrogenous atmosphere (Ar-5 vol% H2 mixture) at 600 °C under the pressure of 0.15 MPa or subjected to 'reduction in the mixture-oxidation in air' (redox) cycling at 600 °C. The YSZ-Ni cermets formed in both treatment conditions were then aged in 'water vapor in A...

Residual stress arisen in fabrication process of Double-Ceramic-Layer Thermal Barrier Coating System (DCL-TBCs) has a significant effect on its quality and reliability. In this work, based on the practical fabrication process of DCL-TBCs and the force and moment equilibrium, a theoretical model was proposed at first to predict residual stress generation in its fabrication process, in which the ...

We present the mechanism and the extent of increase in the oxygen anion diffusivity in Y2O3 stabilized ZrO2 (YSZ) under biaxial lattice strain. The oxygen vacancy migration paths and barriers in YSZ as a function of lattice strain was assessed computationally using density functional theory (DFT) and nudged elastic band (NEB) method. Two competing and non-linear processes acting in parallel wer...