A selective spectrophotometric method has been developed for the determination of cobalt after extraction of its 2-methoxyethyl xanthate complex into molten naphthalene. Cobalt reacts with this xanthate in the ratio of 1 : 2 (metal : ligand ratio) in a pH range of 3.5-9.2 and over an acid range of 2.5-7.0 M. It absorbs strongly at 355 nm. Beer's law is obeyed over the concentration range of 2.5...

In the title mol-ecular complex, [Ni(C3H5OS2)2(C5H4BrN)2], the Ni(2+) cation is located on a centre of inversion and has a distorted octa-hedral N2S4 environment defined by two chelating xanthate ligands and two monodentate pyridine ligands. The C-S bond lengths of the thio-carboxyl-ate group are indicative of a delocalized bond and the O-Csp (2) bond is considerably shorter than the O-Csp (3) ...

A xanthate reagent mixer at a gold mine concentrator was exposed to carbon disulphide by extensive skin contamination with xanthate powder and solution during the reagent mixing process. Absorption of carbon disulphide was confirmed by the detection of urinary 2-thiothiazolidine-4-carboxylic acid (TTCA). Drager colorimetric tube testing during subsequent mixing recorded a maximum concentration ...

Under carefully controlled conditions, the triethylborane-air combination proves to be an efficient radical initiator that allows intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. Depending on both the structures of the xanthate and the olefin, the addition process can be achieved at room temperature or slightly higher.

Flavones were directly alkylated at the C-3 position in moderate yields using a xanthate-based oxidative radical addition procedure. This methodology is a suitable synthetic tool for the direct substitution of the vinylic and unactivated C-H bond of the C ring of the flavone by an alkyl functionality under neutral conditions.

In the title compound, C(5)H(8)O(3)S(2), the C-S and C-O bonds in the xanthate unit are shorter than those linked to it. In the crystal, inversion dimers linked by pairs of O-H⋯O hydrogen bonds occur.

in this paper, the performance evaluation of a two-way hybrid photovoltaic/thermal (pv/t) solar collector was analytically and experimentally carried out. mathematical expressions for operating parameters in glass to glass and glass to tedlar pv/t solar collectors were developed and experimentally validated by a glass to tedlar pv/t solar collector system. also the influence of air flow rate on...

In this study, batch experiments were performed to study the behavior of potassium amyl xanthate surfactant on Fe, Cu and U ions for pretreatment Abu Zeneima sulphate leach liquor. Various parameters, such as amount xanthate, pH, stirring time, sample volume mass (v/m ratio) temperature tested determine optimum conditions. The numerical results obtained support experimental data decreasing iron...

one of the effective methods to improve the thermal efficiency of solar collectors is using nanofluids as the coolant. the present study experimentally investigated the effect of sio2/water nanofluid with 1% mass fraction on the performance of a symmetric collector, i.e. conical solar collector. the conical solar collector with 1 m2 area and normal to the earth was tested in ahvaz, a city in th...