Nanoparticulate zero-valent iron (nZVI) rapidly reacts with oxygen to produce strong oxidants capable of transforming organic contaminants in water. However,the low yield of oxidants with respect to the iron added normally limits the application of this system. Bimetallic nickel-iron nanoparticles (nNi-Fe; i.e., Ni-Fe alloy and Ni-coated Fe nanoparticles) exhibited enhanced yields of oxidants c...

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A series of novel cyano-bridged mixed-valent copper complexes with different nuclearities, where the cyanide group is obtained from the cleavage of a carbon-carbon (C-C) bond in acetonitrile under mild conditions, have been prepared and structurally characterized via a completely in situ synthetic method. The method is catalyzed by 2,2'-bipyridine and 1,10-phenanthroline-based Cu(II) complexes ...

Engineered iron nanoparticles, with sizes smaller than 100 nm, have been of high concern because of their promising capability in environmental remediation. Nanoparticles based on zero-valent iron (nZVI) have the potential not only to migrate in the environment and interact with pollutants but also influence the living organisms by direct impact or by changes of groundwater parameters. The basi...

Thus far, zero-valent iron has been studied mostly for the degradation of structurally simple oneand two-carbon halogenated organic contaminants such as chlorinated methanes, ethanes, and ethenes. In this research, laboratory synthesized particles of nanoscale iron were explored to degrade lindane, also known as -hexachlorocyclohexane, a formerly widely utilized pesticide and well-documented pe...

Controlled diluted aqua regia addition leads to NIR (near infrared) luminescence from aggregated gold nanoparticles at 916 nm. This turn-on luminescence has been observed for gold nanoparticles, regardless of reductants used in their preparation. These aggregated nanoparticles are nontoxic and have been used for bioimaging in human liver carcinoma cells.