Different carboxy-functionalized imidazolium salts have been considered as components of low transition temperature mixtures (LTTMs) in combination with urea. Among them, a novel LTTM based on 1-(methoxycarbonyl)methyl-3-methylimidazolium chloride and urea has prepared characterized by differential scanning calorimetry throughout its entire composition range. This employed for the oxidation bor...

A practical method for the selective and controlled oxidation of thioglycosides to corresponding glycosyl sulfoxides and sulfones is reported using urea-hydrogen peroxide (UHP). A wide range of glycosyl sulfoxides are selectively achieved using 1.5 equiv of UHP at 60 °C while corresponding sulfones are achieved using 2.5 equiv of UHP at 80 °C in acetic acid. Remarkably, oxidation susceptible ol...

Urea-hydrogen peroxide (UHP) was used in the presence of maleic anhydride as mediator in a simple and convenient method for the oxidation in high yield of some thiols to the corresponding disulfides. Peroxymaleic acid formed in situ from the reaction of UHP with maleic anhydride has a key role in this oxidation. Performance of the reaction in various solvents showed that methanol was the solven...

An easy and safe, though only moderately effective method is presented for preparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using the commercially available and easily handled urea-hydrogen peroxide adduct (UHP) as the oxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst)mixtures, at 40 oC for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fu...

background: high amount of heavy metals in sludge is one of the major obstacles to its use on farms. the present study aimed to investigate the possibility of leaching heavy metals from wastewater sludge by fenton method and determine the optimum level of parameters, such as iron, hydrogen peroxide, time, and ph for fenton reaction.   methods: the effects of various parameters, such as ph (2-9)...

Direct urea/hydrogen peroxide fuel cells (DUHP-FCs) can produce electrical energy by recycling urea-rich wastewater. This study expands the commerciality of DUHP-FC removing precious metals from their design. Nickel nanorod/nickel foam (NNR/NF) was fabricated using hydrothermal treatment to be used as anode, and Prussian blue coating deposited potentiostatic electrodeposition onto hydrophilic c...

This study was designed to examine, the effect of Effective aqueous extract Lawsonia inermis leaves as antioxidant on concentration Urea ,Criatinine and Histological kidneys in Albino male Rats exposed hydrogen peroxide induced oxidative stress. showed that 0.5% leds significant increase (P<0.05( serum urea creatinine comparing with control group. While (50mg/kg) led decrease (P<0.05) com...