The electroanalytic performances of glassy carbon paste electrode (GCPE), multi-walled carbon nanotube (MWCNT)-GCPE and double-walled carbon nanotube (DWCNT)-GCPE, which include HNO3 washed/unwashed materials, were compared by monitoring cyclic voltammograms of potassium ferricyanide and catechol. Electrodes were prepared by introducing proper amount of DWCNT and MWCNT into GCPE. First untreate...

We have demonstrated near-edge X-ray absorption fine structure (NEXAFS) spectroscopy as a particularly useful and effective technique for simultaneously probing the surface chemistry, surface molecular orientation, degree of order, and electronic structure of carbon nanotubes and related nanomaterials. Specifically, we employ NEXAFS in the study of single-walled carbon nanotube and multi-walled...

Submitted to the NANOTUBE'04 Conference: CVD Synthesis of Single-Walled Carbon Nanotubes from Alcohol

The influence of flexible walls on the self-diffusion of CH4 in an isolated single walled carbon nanotube, as an example, is studied by molecular dynamics simulations. By simulating the carbon nanotube as a flexible framework we demonstrate that the flexibility has a crucial influence on self-diffusion at low loadings. We show how this influence can be incorporated in a simulation of a rigid na...

Strong quantum confinement and low dielectric screening impart single-walled carbon nanotubes with exciton-binding energies substantially exceeding kBT at room temperature. Despite these large binding energies, reported photoluminescence quantum yields are typically low and some studies suggest that photoexcitation of carbon nanotube excitonic transitions can produce free charge carriers. Here ...

Internal functionalization of single-walled nanotubes is an attractive, yet difficult challenge in nanotube materials chemistry. Here we report single-walled metal oxide nanotubes with covalently bonded primary amine moieties on their inner wall, synthesized through a one-step approach. Conclusive molecular-level structural information on the amine-functionalized nanotubes is obtained through m...

Carbon nanotubes (CNT) are one of the most widely used nonmaterials. It is applied in various fields due to its special physical characteristics, excellent electronic performance and stable chemical activity. There are two types of CNT occur (a) Single walled carbon nanotube (b) Multiwalled carbon nanotube. As their names shows, SWNTs consist of a single, cylindrical graphene layer, where as MW...

carbon nanotube is investigated based on an elastic multi-layer shell model with van der Waals interaction taken into consideration. The multi-walled carbon nanotube is described as an individual elastic shell and the interlayer friction is negligible between the inner and outer tubes in the proposed model. And the Donnell equations of cylindrical shells are employed to describe the nonlinear b...

excellent mechanical properties of carbon nanotubes (cnts) make them outstanding candidate reinforcements to enhance mechanical properties of conventional composites. the glass/polyester composites are widely used in many industries and applications. improving the mechanical properties of such composites with addition of cnts can increase their applications. in this research, multi-walled carbo...

We use electrostatic force microscopy and scanned gate microscopy to probe the conducting properties of carbon nanotubes at room temperature. Multiwalled carbon nanotubes are shown to be diffusive conductors, while metallic single-walled carbon nanotubes are ballistic conductors over micron lengths. Semiconducting single-walled carbon nanotubes are shown to have a series of large barriers to co...