The aim of the present research work was to determine the Phyto-constituents in fraction collected from ethanolic extract of Pericampylus glaucus leaf using the GC and Mass spectrometry. The Phyto-chemical screening of fraction from ethanolic extract of Pericampylus glaucus leaves were carried out with the help of Perkin-Elmer GC followed by Mass Spectrometry. The GC-MS chromatogram of Pericamp...

The direct synthesis of 1,1?,2,2?-tetralithioferrocene from 1,1?,2,2?-tetrabromoferrocene is reported. In addition, the related 1,1?,2,2?,3,3?-hexalithioferrocene also described, prepared directly 1,1?,2,2?,3,3?-hexabromoferrocene. These lithioferrocenes may be isolated as orange red (tetralithio) and (hexalithio) powders, respectively. When these are in situ reacted with chlorotrimethylsilane,...

Starting from tris(trimethylsilyl)silane the novel 2-chloro-3,4-bis-tris(trimethylsilyl)silyl-cyclo-diphospha-diazenium-tetrachloridogallate salt (7) was prepared in a six step synthetic procedure including the synthesis of N-tris(trimethylsilyl)silyl-aminodichlorophosphine (4) and 1,3-dichloro-2,4-bis-tris(trimethylsilyl)silyl-cyclo-diphospha-diazane (5). All intermediate products along the re...

A general procedure for the nucleophilic addition of organozinc halides with nitrones in the presence of trimethylsilyl chloride has been developed. Trimethylsilyl chloride was found to be both an indispensable reaction promoter and a ready hydroxylamine protective agent in these reactions. The produced O-(trimethylsilyl)hydroxylamines can be easily reduced into corresponding amines just by a z...