abstractbackground and objectives:the phosphorus is second limiting nutrient in soil for crop production after nitrogen. mobility and availability of phosphorus (p) in soils is affected by phosphorus desorption characteristics. information about the effect of organic matter on kinetics and thermodynamics of p desorption in calcareous soils of east azerbaijan province is limited. the objective o...

Human serum albumin (HSA) is the most abundant protein in the blood plasma. Drug binding to HSA is crucial to study the absorption, distribution, metabolism, efficiency and bioavailability of drug molecules. In this study, isothermal titration calorimetry and molecular dynamics simulation of HSA and its complex with indometacin (IM) were performed to investigate thermodynamics parameters and th...

In their perspective ‘‘Computational studies on organic reactivity in ionic liquids’’ Chiappe and Pomelli have written a short paragraph excluding COSMO-RS as a potential method for estimating reaction thermodynamics in ionic liquids. They write: ‘‘COSMO-RS, a model based on a simplified version of the polarizable continuummodel, which is strongly parameterized, has been used to estimate the th...

I discuss the concept of fractional exclusion statistics (FES) and I show that in order to preserve the thermodynamic consistency of the formalism, the exclusion statistics parameters should change if the species of particles in the system are divided into subspecies. Using a simple and intuitive model I deduce the general equations that have to be obeyed by the exlcusion statistics parameters ...

We present the state of the art on the modern mathematical methods of exploiting the entropy principle in thermomechanics of continuous media. A survey of recent results and conceptual discussions of this topic in some well-known non-equilibrium theories (Classical irreversible thermodynamics CIT, Rational thermodynamics RT, Thermodynamics of irreversible processes TIP, Extended irreversible th...