A comprehensive and hierarchical optimization of a joint hydrogen and syngas combustion mechanism has been carried out. The Kéromnès et al. (Combust Flame, 2013, 160, 995-1011) mechanism for syngas combustion was updated with our recently optimized hydrogen combustion mechanism (Varga et al., Proc Combust Inst, 2015, 35, 589-596) and optimized using a comprehensive set of direct and indirect ex...

In this paper, an integrated coke dry quenching combined gasification system using coke oven gas and steam to quench the incandescent coke is proposed. The distinct advantages of the system include energy conservation, pollution reduction, coke quality improvement and full use of resources. Based on the minimization of the Gibbs free energy, the flow rate and composition of the syngas are predi...

Ethanol synthesis from CH4 and syngas on a Cu-Co/TiO2 catalyst is studied using experiments, density functional theory (DFT) and microkinetic modelling. The experimental results indicate that the active sites of ethanol synthesis from CH4 and syngas are Cu and CoO, over which the ethanol selectivity is approximately 98.30% in a continuous stepwise reactor. DFT and microkinetic modelling results...

Rubber wood (Ficus elastica) is one the biomass waste that can be used as raw material for a gasification process and has a calorific value of 4,069 cal/gram. Gasification is a process to convert a solid fuel to syngas (CO, CH4, and H2) through a combustion process using limited air between 20% to 40% of air stoichiometry. Depending on the direction of airflow, the gasifiers are classified as u...

The microwave induced pyrolysis of the microalgae Scenedesmus almeriensis and its extraction residue was carried out at 400 and 800°C. The results show that it is possible to obtain a gas fraction with a high content (c.a. 50vol.%) in H2 from both materials, regardless of the pyrolysis temperature. Furthermore, an outstanding syngas production and high gas yields were achieved. The maximum syng...

Ni-YSZ anode supported solid oxide fuel cells (ASCs) were tested under various simulated syngas. There was no voltage degradation of the cell operated on 41%H2-7%CH4-6%CO-11%CO2-35%H2O fuel condition for nearly 450 hours. However, the high vapor content reduced the open circuit voltage (OCV) and discharge voltage. The cells run steadily with most dry syngas until the simulated reforming tempera...

In this paper, an innovative power plant, constituted by a gas turbine in combined-cycle fuelled by a synthesis gas (or syngas), produced in a local biomass gasifier, is analyzed. The plant is integrated with an external combustion system, fed by cellulosic biomass, connected to a heat exchanger able to increase the air temperature, as in a regenerative cycle. The combustion products pass throu...

The catalytic combustion of syngas/air mixtures over Pt has been investigated numerically in a channel-flow configuration using 2D steady and transient computer codes with detailed hetero-/homogeneous chemistry, transport, and heat transfer mechanisms in the solid. Simulations were carried out for syngas compositions with varying H2 and CO contents, pressures of 1 to 15 bar, and linear velociti...

Gasification of organic wastes coupled to syngas fermentation allows the recovery of carbon in the form of commodity chemicals, such as carboxylates and biofuels. Acetogenic bacteria ferment syngas to mainly two-carbon compounds, although a few strains can also synthesize four-, and six-carbon molecules. In general, longer carbon chain products have a higher biotechnological (and commercial) va...

Methanol syntheses at low temperature in a liquid medium present an opportunity for full syngas conversion per pass. The aim of this work was to study the role of solvents polarity on low-temperature methanol synthesis reaction using eight different aprotic polar solvents. A “once through” catalytic system, which is composed of Cu nanoparticles and sodium methoxide, was used for methanol synthe...