Single-walled carbon nanotubes (SWCNTs) have demonstrated a remarkable capacity for self-assembly into nanobundles through intermolecular van der Waals interactions, bestowing these agglomerates extraordinary mechanical, thermal, and electrical properties. However, how to improve the binding ability of SWCNT bundles to mitigate the delamination and sliding effects between individual nanotubes r...

We postulate that an equivalent continuum structure (ECS) of a single-walled carbon nanotube (SWCNT) is a hollow cylinder with mean radius and length equal to that of the SWCNT, and find the thickness of the ECS so that its mechanical response in free vibrations is the same as that of the SWCNT. That is, for mechanical deformations, the ECS is energetically equivalent to the SWCNT. We use MM3 p...

Biomolecule cytochrome c (Cty c), a small molecule of a chain of amino acids with extraordinary electron transport, was helically wrapped around a semiconductive single-wall carbon nanotube (s-SWCNT) to form a molecular building block for uncooled infrared detection with two uniquely designed functionalities: exciton dissociation to free charge carriers at the heterojunction formed on the s-SWC...

Although carbon nanomaterials such as single-walled carbon nanotubes (SWCNT) are becoming increasingly prevalent in manufacturing, there is little knowledge on the environmental fate of these materials. Environmental degradation of SWCNT is hindered by their highly condensed aromatic structure as well as the size and aspect ratio, which prevents intracellular degradation and limits microbial de...

Sonication process is regularly adopted for dispersing single-walled carbon nanotubes (SWCNTs) in an aqueous medium. This can be achieved by either covalent functionalization of SWCNTs with strong acid or by noncovalent functionalization using dispersants that adsorb onto the surface of SWCNTs during dispersion. Because the dispersion process is usually performed using sonication, unintentional...

Three types of single-walled carbon nanotube (SWCNT) homogeneous epoxy composites with different SWCNT loadings (0.01–15%) have been evaluated for electromagnetic interference (EMI) shielding effectiveness (SE) in the X-band range (8.2–12.4 GHz). The effect of the SWCNT structure including both the SWCNT aspect ratio and wall integrity, on the EMI SE have been studied and are found to correlate...

The cellular toxicity of three types of carbon nanoparticles, namely HiPco single-walled carbon nanotubes (SWCNT), arc discharge SWCNT and Printex 90 carbon black nanoparticles, was studied on three different cell models including the human alveolar carcinoma epithelial cell line (A549), the normal human bronchial epithelial cell line (BEAS-2B) and the human keratinocyte cell line (HaCaT) using...

Two different kinds of SWCNT functionalized zigzag edge BN nanoribbons with n chains (n-ZBNNRs), namely, (a) B-edge functionalized by (m,m)SWCNT and N-edge modified with H (nZBNNR-B-(m,m)SWCNTs); and (b) the B-edge modified with H and the N-edge functionalized by (m,m)SWCNT (nZBNNR-N-(m,m)SWCNTs), have been predicted. Amazingly, we find that unlike the semiconducting and nonmagnetic H-modified ...

We have examined the electrocatalytic activity of iron phthalocyanine (FePc) and perchlorinated 16(Cl)FePc for oxygen reduction reaction (ORR) in alkaline medium with two molecules either adsorbed on external surface single-wall carbon nanotubes (SWCNT) or covalently anchored via an axial pyridine ligand pyridine-functionalized (py-SWCNT). Regardless particular type, ORR is higher when substrat...

Redox reaction [Fe(CN)6] 3– / [Fe(CN)6] 4– has been studied with a Single-Walled Carbon Nanotube (SWCNT)-coated Glassy Carbon Electrode (GCE), SWCNT-coated Gold Electrode (GE) and a lab-made SWCNT-TPLF (SWCNT-Thin-Paper-Like-Film) Electrode. The SWCNT-modified electrode has shown a well-defined redox peak compared to bare electrodes. Cyclic voltammetry was used in 50.0 × 10–3 M aqueous solution...