A mathematical model is described and applied for adsorption process of ethyl acetate from supercritical CO2 stream on activated carbon particles. This model has the ability of illustrating variation of effluent concentration towards different parameters such as flow rate, temperature and pressure. In this research, a vast area of operational conditions is experienced. Mass transfer resistance ...

5-methylresorcinol and the technical mixture of oil-shale phenolic compounds were applied for carbon aerogel preparation. Gels, which were prepared via base catalyzed polymerization were dried under supercritical conditions and subsequent pyrolysis of obtained dry aerogels led to carbon aerogels. Activation of carbon aerogel with CO2 and H2O was performed and porosity and the specific surface a...

Fish oil was extracted from the viscera of African Catfish using supercritical carbon dioxide (SC-CO(2)). A Central Composite Design of Response Surface methodology (RSM) was employed to optimize the SC-CO(2) extraction parameters. The oil yield (Y) as response variable was executed against the four independent variables, namely pressure, temperature, flow rate and soaking time. The oil yield v...

Copolymeric products from 2-methylaziridine and carbon dioxide showed sharp and rapid phase transitions in response to both temperature and pH; the responsive property can be controlled by varying the reaction conditions whilst maintaining the supercritical state.

a r t i c l e i n f o A brief overview of the literature relating to electrochemical studies and processes undertaken in supercritical fluids is presented. This review mostly concerns carbon dioxide and hydrofluorocarbons, given the accessibility of their supercritical states, and does not consider the emerging body of research in expanded phase electrochemistry.

In this paper, supercritical carbon dioxide (SC CO2) was first reported to help prepare unique flexible free-standing graphene oxide/nanofiber (GC) films. A novel hierarchical superior electrode material with polypyrrole (PPy) deposited on GO/CNF-SC (GC-SC) films was prepared via an in situ polymerization process. Our experimental results indicate that SC CO2 can not only enlarge the space betw...

Drill mud is a fluid which is used in oil extraction industries in order to cool and lubricate the drill bit. Due to containing numerous toxic components, it is considered as a hazardous waste which must be treated before discharging to the environment. Current separation techniques for drill cutting treatment can be categorized into three main categories of physical (dewatering), physiochemica...

A fully integrated continuous process for homogeneous catalysed reactions in scCO(2) has been developed exploiting the tunable solvent properties of scCO(2). A heated condenser situated above the reaction zone leads to a phase split under isobaric conditions resulting in efficient catalyst retention and recirculation. Continuous isomerisation of allylic alcohols was carried out for over 200 hou...