in this paper, a cfd model of syngas flow in slurry bubble column was developed. the model is based on an eulerian-eulerian approach and includes three phases: slurry of solid particles suspended in paraffin oil and syngas bubbles. numerical calculations carried out for catalyst particles, bubble coalescence and breakup included bubble-fluid drag force and interfacial area effects. also, the ef...

The application of silica-supported TEMPO as a recyclable catalyst in the Anelli oxidation of alcohols is reported. The catalyst is easily obtained in a one-step reductive amination procedure starting from a commercially available aminopropyl-functionalized silica. Details of the synthesis of the supported catalyst and its analysis by MAS NMR are presented. Various alcohol oxidations according ...

poly(4-vinylpyridine)-supported copper iodide nanoparticles is reported as a new, green and recyclable catalyst for the synthesis of aryl-14h-dibenzo [a-o] xanthenes under solvent-free conditions. this catalyst can be recovered by simple filtration and recycled up to 8 consecutive runs without any loss of their efficiency.

The nano-Fe3O4 particles were prepared by hydrothermal method. Cellulose-based magnetic Fe3O4 was prepared by adding cellulose solution dissolved in sodium hydroxide / thiourea / urea system. The basic protease was used as the catalyst and glutaraldehyde was used as the crosslinking agent, The production of magnetic recyclable immobilized enzyme can greatly reduce the cost of hydrolysis of slud...

The synthesis of recyclable ionic liquid-supported imidazolidinone catalyst I and its application in 1,3-dipolar cycloaddition of nitrone with α,β-unsaturated aldehyde with high performance were described. Most importantly, the catalyst I can be recovered and recycled for up to five runs without observing significant decrease in catalytic activity.

A recyclable catalyst, Ni(0)-CMC-Na, composed of nickel colloids dispersed in a water soluble bioorganic polymer, sodium carboxymethylcellulose (CMC-Na), was synthesized by a simple procedure from readily available reagents. The catalyst thus obtained is stable and highly active in alkene hydrogenations.

isotactic poly (1-butene), ipbu-1, was synthesized by using a metallocene catalyst. the thermodynamic phase behavior of polymer–organic solvents systems is very important in every polymer application.  in this paper, the solid–liquid equilibrium of ipbu-1 with different organic solvents (1-heptyne, cyclo octane) was studied by a mathematical model. by considering the experiments temperature-mol...

polyethylene glycol was easily grafted to silica gel and used as a solid–liquid phase transfer catalyst in the reduction of aromatic nitro compounds. this silica-grafted polyethylene glycol is proved to be an efficient heterogeneous catalyst in the reduction of nitroarenes to the corresponding aromatic amines with zinc powder in water. the reduction reactions proceeded efficiently with excellen...

Dowex-50W-hyodrgen ion exchange resin was used as a reusable catalyst for the synthesis of oxazoline, imidazoline and thiazoline derivatives through condensation reaction between arylnitriles and 2-aminoalcohol, ethylenediamine or 2-aminoethanthiol. This process provides several advantages such as excellent yields of the products, simple operation, convenient separation and inexpensive and recy...