نتایج جستجو برای: so2 oxidation
تعداد نتایج: 122483 فیلتر نتایج به سال:
Motivated by the need to develop instrumental techniques for characterizing organic aerosol aging, we report on the performance of the Toronto Photo-Oxidation Tube (TPOT) and Potential Aerosol Mass (PAM) flow tube reactors under a variety of experimental conditions. The PAM system was designed with lower surface-area-tovolume (SA/V) ratio to minimize wall effects; the TPOT reactor was designed ...
abstract part one: the electrode oxidation potentials of a series of eighteen n-hydroxy compounds in aqueous solution were calculated based on a proper thermodynamic cycle. the dft method at the level of b3lyp-6-31g(d,p) was used to calculate the gas-phase free energy differences ,and the polarizable continuum model (pcm) was applied to describe the solvent and its interaction with n-hydroxy ...
The effect of increased reaction rates of stabilized Criegee intermediates (sCIs) with SO2 to produce sulfuric acid is investigated using data from two different locations, SMEAR II, Hyytiälä, Finland, and Hohenpeissenberg, Germany. Results from MALTE, a zero-dimensional model, show that using previous values for the rate coefficients of sCI+SO2, the model underestimates gas phase H2SO4 by up t...
We used thermochemical equilibrium calculations to constrain the oxygen fugacity ( fO2 ) of volcanic gases on Io. Three types of calculations were done: (1) Upper limits for fO2 from Voyager IRIS upper limits for the SO3/SO2 ratio and the O3 abundance in the Loki volcanic plume; (2) lower limits for fO2 from the observed SO/SO2 ratio in Io’s atmosphere; (3) oxygen fugacities as a function of te...
This thesis presents a new experimental setup for surface analysis studies, incorporating chemical information from infrared reflection absorption spectroscopy (IRAS) and quantitative information from quartz crystal microbalance (QCM). The integrated IRAS/QCM surface analysis system enables in situ studies to be conducted of the metal/atmosphere interaction on a sub-monolayer level. In combinat...
The photochemistry of the stratosphere of Venus was modeled using an updated and expanded chemical scheme, combined with the results of recent observations and laboratory studies. We examined three models, with H2 mixing ratio equal to 2 x 10 3, 5 x 10t, and I x 103, respectively. All models satisfactorily account for the observations of CO, 02, 0 2 CA), and SO2 in the stratosphere, but only th...
We studied the oxidation of dimethylsulfide (DMS) in the marine boundary layer (MBL) with a onedimensional numerical model and focused on the influence of halogens. Our model runs show that there is still significant uncertainty about the end products of the DMS addition pathway, which is especially caused by uncertainty in the product yield of the reaction of the intermediate product methyl su...
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