نتایج جستجو برای: selective oxidation of propane

تعداد نتایج: 21188084  

Journal: :Physical chemistry chemical physics : PCCP 2011
Ming-Lei Yang Yi-An Zhu Chen Fan Zhi-Jun Sui De Chen Xing-Gui Zhou

Self-consistent periodic slab calculations based on gradient-corrected density functional theory (DFT-GGA) have been conducted to examine the reaction network of propane dehydrogenation over close-packed Pt(111) and stepped Pt(211) surfaces. Selective C-H or C-C bond cleaving is investigated to gain a better understanding of the catalyst site requirements for propane dehydrogenation. The energy...

Journal: :Applied Catalysis B-environmental 2021

Co3O4 catalysts were prepared via carbonate precipitation at different pH, characterized using TG/DTA, FTIR, XRD, Raman, N2 adsorption and TPR techniques, tested in the total oxidation of toluene or propane. The pH may affect composition cobalt oxide precursors as well physicochemical properties performance catalysts. By controlling 9.5, a catalyst with smallest crystalline size, largest surfac...

Journal: :Biotechnology and bioengineering 2010
Jonathan O Sharp Christopher M Sales Lisa Alvarez-Cohen

Propane-induced cometabolic degradation of n-nitrosodimethylamine (NDMA) by two propanotrophs is characterized through kinetic, gene presence, and expression studies. After growth on propane, resting cells of Rhodococcus sp. RR1 possessed a maximum transformation rate (v(max,n)) of 44 ± 5 µg NDMA (mg protein)(-1) h(-1); the rate for Mycobacterium vaccae (austroafricanum) JOB-5 was modestly lowe...

Journal: :Environmental science. Processes & impacts 2015
Kristin M Mikkelson Carissa L Homme Dong Li Jonathan O Sharp

Biologically activated carbon (BAC) can be used in both municipal water and hazardous waste remediation applications to enhance contaminant attenuation in water; however, questions remain about how selective pressures can be applied to increase the capabilities of microbial communities to attenuate recalcitrant contaminants. Here we utilized flow-through laboratory columns seeded with municipal...

Journal: : 2022

In the scientific literature problem of obtaining highly selective aluminosilicate catalysts is related to study influence nature active centers (acidity their surface) on catalytic activity. some cases a linear dependency can be observed between rate acidity and catalytical The alumosilicates, in its turn, considerably dependent mode preparation. case preparing alumosilicates by joint precipit...

Journal: :European Journal of Inorganic Chemistry 2021

Dinuclear iron peroxido complexes are important intermediates for selective oxidation reactions. A detailed kinetic study of the reaction benzoyl chloride (BzCl) with a dinuclear non-heme cis end-on complex ligand EtHPTB (N,N,N′,N′-tetrakis[(N-ethyl-2-benzimidazolyl)methyl]-2-hydroxy-1,3-diamino-propane) had been performed. The starting complex, can be obtained either by iron(II) O2 or instead,...

2014
Sebastian Reinelt Daniel Steinke Helmut Ritter

In this work we report the synthesis of thermo-, oxidation- and cyclodextrin- (CD) responsive end-group-functionalized polymers, based on N,N-diethylacrylamide (DEAAm). In a classical free-radical chain transfer polymerization, using thiol-functionalized 4-alkylphenols, namely 3-(4-(1,1-dimethylethan-1-yl)phenoxy)propane-1-thiol and 3-(4-(2,4,4-trimethylpentan-2-yl)phenoxy)propane-1-thiol, poly...

Journal: :iranian chemical communication 2014
mehdi nabati mehrdad mahkam

2,6-diaminopyridine is extensively used as a pharmaceutical intermediate and a hair dye coupler as oxidation formulations. it is soluble in protic solvents. primary and secondary amines are n-methylated by various methods such as direct alkylation of amines with hofmann mechanism, but in many of these methods due to overalkylations, we earn a mixture of amino products. consequently, they aren't...

Journal: :Applied and environmental microbiology 2009
Kristin Skinner Lynda Cuiffetti Michael Hyman

The filamentous fungus Graphium sp. (ATCC 58400) grows on gaseous n-alkanes and diethyl ether. n-Alkane-grown mycelia of this strain also cometabolically oxidize the gasoline oxygenate methyl tert-butyl ether (MTBE). In this study, we characterized the ability of this fungus to metabolize and cometabolize a range of cyclic ethers, including tetrahydrofuran (THF) and 1,4-dioxane (14D). This stra...

Journal: :iranian journal of chemistry and chemical engineering (ijcce) 2002
mahammad mahmoodi hashemi yousef ahmadibeni

the polymer supported hypochlorite ion is a facile selective oxidizing agent for the oxidation of various alcohols to aldehydes and ketones. similarly is successfully oxidizes various hantzsch type 1,4- dihydropyridines to corresponding pyridines.

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