Titanium dioxide sTiO2, with the rutile structured was grown on s0001d oriented GaN and s0001d Al0.33Ga0.67N/GaN heterostructure field effect transistor sHFETd structures by molecular beam epitaxy. X-ray diffraction showed s100dTiO2 i s0001dGaNsAlGaNd and f001gTiO2 i k112̄0lGaNsAlGaNd with three rotational variants of the TiO2. Transmission electron microscopy of 50 nm thick TiO2 films on GaN an...

TiO2 nanopowder is prepared by simple sol-gel method using starting material as titanium isopropoxide with methanol and annealed at 600°C, 700°C and 800°C for 1 hour in air. X-ray diffraction pattern revealed the presence of both anatase and rutile phase in TiO2 specimens annealed at different temperatures. It is observed that the content of rutile phase and crystallite size increases with incr...

Anatase, one of the polymorphs titanium dioxide (TiO2), has become most widely used semiconductor for photocatalytic materials due to its chemical and physical properties. However, researchers have been studying use alternative (e.g., ZnO, N-doped, C-doped TiO2) improve activity cementitious materials. In this paper, we propose a modification lightweight concrete by introducing mixed phases dio...

An interatomic potential model has been developed for molecular-dynamics simulations of TiO2 ~rutile! based on the formalism of Streitz and Mintmire @J. Adhes. Sci. Technol. 8, 853 ~1994!#, in which atomic charges vary dynamically according to the generalized electronegativity equalization principle. The present model potential reproduces the vibrational density of states, the pressure-dependen...

Using a simple hydrothermal synthesis, the crystal structure of TiO2 nanoparticles was controlled from rutile to anatase using a sugar alcohol, D-sorbitol. Adding small amounts of D-sorbitol to an aqueous TiCl4 solution resulted in changes in the crystal phase, particle size, and surface area by affecting the hydrolysis rate of TiCl4. These changes led to improvements of the solar-to-electrical...

ont matter & 2012 n.2012.02.009 thors. : wei-mingdeng@f .edu (G. Cao). Abstract Wulff-shaped and nanorod-like nanoporous mesocrystals constructed from ultrathin rutile TiO2 nanowires were successfully fabricated for the first time in the presence of the surfactant sodium dodecyl benzene sulfonate (SDBS). SDBS played a key role in the homoepitaxial selfassembly process, in which titanate nanowir...

A synergistic effect between anatase and rutile TiO2 is known, in which the addition of rutile can remarkably enhance the photocatalytic activity of anatase in the degradation of organic contaminants. In this study, mixed-phase TiO2 nanocomposites consisting of anatase and rutile nanoparticles (NPs) were prepared for use as photoanodes in dye-sensitized solar cells (DSSCs) and were characterize...

It is known that TiO2 exhibits good photocatalytic properties which could be used in various commercial applications such as water and air purification or photo-induced biodegradation of microbes. TiO2 occurs in nature in the form of three crystal polymorphs: anatase, brookite and rutile. For photocatalytic applications only anatase and rutile are of interest, however anatase shows greater phot...

It is demonstrated that the support effects play a crucial role in the gold nanocatalysis. Two types of support are considered—the “inert” support of hexagonal boron nitride (h-BN) with the N and B vacancy defects and the “active” support of rutile TiO2(110). It is demonstrated that Au and Au2 can be trapped effectively by the vacancy defects in h-BN. In that case, the strong adsorption on the ...