The behaviour of adenine and 2’-deoxyadenosine-5’-monophosphate (dAMP) at positive surface potentials of a silver working electrode was investigated using surface-enhanced Raman scattering (SERS). The use of positive potentials in the presence of adenine or dAMP leads to a rapid accumulation of an intense spectrum. It is proposed that complexes of adenine (dAMP) with silver generate the observe...

We characterize the cd-indices of Gorenstein* posets of rank 5, equivalently the flag f -vectors of Gorenstein* order complexes of dimension 3. As a corollary, we characterize the f -vectors of Gorenstein* order complexes in dimensions 3 and 4. This characterization rise a speculated intimate connection between the f -vectors of flag homology spheres and the f -vectors of Gorenstein* order comp...

The reversible thermochromic behaviour of homoleptic [{V(OR)(4)}(n)] complexes in solution [R = Pr(i) (product I), Bu(s) (B(s)), Nep (N) and Cy (C)] is accounted for the existence of an aggregation equilibrium involving dimeric and monomeric species in which vanadium(iv) is respectively five- and four-coordinate. Bulky R groups such as Bu(t) and Pe(t) (tert-pentoxide) prevent aggregation and th...

Taking the `1-completion and the topological dual of the singular chain complex gives rise to `1-homology and bounded cohomology respectively. Unlike `1-homology, bounded cohomology is quite well understood by the work of Gromov and Ivanov. We derive a mechanism linking isomorphisms on the level of homology of Banach chain complexes to isomorphisms on the level of cohomology of the dual Banach ...

We characterize the cd-indices of Gorenstein* posets of rank 5, equivalently the flag f -vectors of Gorenstein* order complexes of dimension 3. As a corollary, we characterize the f -vectors of Gorenstein* order complexes in dimensions 3 and 4. This characterization rise a speculated intimate connection between the f -vectors of flag homology spheres and the f -vectors of Gorenstein* order comp...

Taking the `1-completion and the topological dual of the singular chain complex gives rise to `1-homology and bounded cohomology respectively. In contrast to `1-homology, major structural properties of bounded cohomology are well understood by the work of Gromov and Ivanov. Based on an observation by Matsumoto and Morita, we derive a mechanism linking isomorphisms on the level of homology of Ba...

Taking the ℓ 1-completion and the topological dual of the singular chain complex gives rise to ℓ 1-homology and bounded cohomology respectively. Unlike ℓ 1-homology, bounded cohomology is very well understood by the work of Gromov and Ivanov. Based on an observation by Matsumoto and Morita, we derive a mechanism linking isomorphisms on the level of homology of Banach chain complexes to isomorph...