in this research, the effect of the first order magnetic field on the ground-state of a centered hydrogenic donor impurity in a gaas/alas spherical quantum dot has been calculated. the perturbation method has been used within the framework of effective mass approximation for these calculations. overall, the analysis shows that a proper choice of quantum dot radius and magnetic field can signifi...

Colloidal quantum dot solids combine convenient solution-processing with quantum size effect tuning, offering avenues to high-efficiency multijunction cells based on a single materials synthesis and processing platform. The highest-performing colloidal quantum dot rectifying devices reported to date have relied on a junction between a quantum-tuned absorber and a bulk material (e.g., TiO(2)); h...

Colloidal quantum dot photovoltaics combine low-cost solution processing with quantum size-effect tuning to match absorption to the solar spectrum. Rapid advances have led to certified solar power conversion efficiencies of over 7%. Nevertheless, these devices remain held back by a compromise in the choice of quantum dot film thickness, balancing on the one hand the need to maximize photon abso...

The UNSW node of the Hot Carrier Solar Cell project is investigating the phonon dispersions properties of ordered quantum dot arrays. The object is to determine the potential to modify the allowed phonon energies such as to block the decay of optical phonons, this being the principle decay mechanism for hot photo-generated carriers in an absorber material. This will then offer the possibility o...

Recent advances in quantum dot surface passivation have led to a rapid development of high-efficiency solar cells. Another critical element for achieving efficient power conversion is the charge neutrality of quantum dots, as charge imbalances induce electronic states inside the energy gap. Here we investigate how the simultaneous introduction of metal cations and halide anions modifies the cha...

a noninteracting quantum-dot arrays side coupled to a quantum wire is studied. transport through the quantum wire is investigated by using a noninteracting anderson tunneling hamiltonian. the conductance at zero temperature develops an oscillating band with resonances and antiresonances due to constructive and destructive interference in the ballistic channel, respectively. moreover, we have fo...

We report colloidal quantum dot solar cells fabricated under ambient atmosphere with an active area of 2.9 mm(2) that exhibit 3.6% solar power conversion efficiency. The devices are based on PbS tuned via the quantum size effect to have a first excitonic peak at 950 nm. Because the formation of native oxides and sulfates on PbS leads to p-type doping and deep trap formation and because such dop...

We have investigated two complementary nanostructures, nanocavity and nanopillar arrays, for light absorption enhancement in depleted heterojunction colloidal quantum dot (CQD) solar cells. A facile complementary fabrication process is demonstrated for patterning these nanostructures over the large area required for light trapping in photovoltaic devices. The simulation results show that both p...