The influence of catalysts on the compositions of char and pyrolysis oil obtained by pyrolysis of wood biomass with pulse current heating was studied. The effects of catalysts on product compositions were analyzed using GC-MS and TEM. The compositions of some aromatic compounds changed noticeably when using a metal oxide species as the catalyst. The coexistence or dissolution of amorphous carbo...

The major challenge for the pyrolytic conversion of lignocellulosic materials into crude bio-oil is the poor quality of the final product. Several strategies (addition of solvents, production of emulsions, and extraction with biodiesel) have been studied to improve its fuel properties. The extraction with biodiesel is an interesting solution because it allows direct utilization of some bio-oil ...

This life cycle assessment (LCA) evaluates and quantifies the environmental impacts of the production of hydrogen and transportation fuels from the fast pyrolysis and upgrading of corn stover. Input data for this analysis come from Aspen Plus modeling, a GREET model database and a U.S Life Cycle Inventory Database. SimaPro 7.3 software is employed to estimate the environmental impacts. The resu...

This study was aimed to investigate the effect of mineral matter of Göynük oil shales (GOS) on pyrolysis and product evolution. Organic part was separated from mineral matter before pyrolysis in an isothermal pyrolysis reactor. In the demineralization step, carbonate, pyrite and silicates were removed from kerogen by using HCl, HNO3 and HF, respectively. Thereafter all samples were pyrolized in...

Pyrolysis is an attractive thermal conversion technology used to produce bio-oil and some chemicals. In this study, we investigated the pyrolysis of sewage sludge under N2 and CO2 atmosphere at various temperatures (350-750°C) in a rotating fixed bed reactor. For under N2 atmosphere, thermal gravimetric analysis (TGA) shows two major reaction peaks centered at 300 and 500°C. However, if CO2 was...

In this paper the possibility of using the pyrolysis oil derived from waste tyres as a collector in flotation of coal was evaluated. The pyrolysis oil was obtained at the initial and final pyrolysis temperatures of 400 and 700 C, respectively, and the heat holding time of 30 min. Flotation results indicated that the pyrolysis oil emulsion showed stronger collecting ability than diesel and the c...

The cost of chemicals prohibits many technically feasible enhanced oil recovery methods to be applied in oil fields. It is shown that by-products from oil palm processing can be a source of valuable chemicals. Analysis of the pyrolysis oil from oil palm shells, a by-product of the palm oil industry, reveals a complex mixture of mainly phenolic compounds, carboxylic acids, and aldehydes. The phe...

Biocrude (fast pyrolysis oil from wood) was hydrotreated to minimize the negative aspects of this fuel. The instability of the oil was reduced by reaction of the most unstable functional groups. Concurrently, the oxygenated component of the oil was also reduced, resulting in an improved energy density. Changes in the physical handling properties were also modified. All of this change was accomp...

Peatlands represent a globally important carbon store; however, the human exploitation of this ecosystem is increasing both the frequency and severity of fires on drained peatlands. Yet, the interactions between the hydrological conditions (ecotopes), the fuel types being burned, the burn severity, and the charring temperatures (pyrolysis intensity) remain poorly understood. Here we present a p...

An unresolved and debated aspect in the fast pyrolysis of biomass is whether the bio-oil exits as a vapor or as an aerosol from the pyrolytic reactor. The determination of the bio-oil transport phase will have direct and significant impact on the design of fast pyrolysis systems. Optimization of both the removal of particulate matter and collection of bio-oil will require this information. In a...