Abstract To prevent volcanic ash corrosion using thermal barrier coatings (TBCs), a novel method Al 2 O 3 -modification was proposed to reduce molten CMAS wettability on TBCs surface through lotus effect. Plasma spray-physical vapor deposition (PS-PVD), third-generation for fabrication, adopted deposit 7YSZ with feather-like microstructure. Then, modification introduced fabricate dense overlay ...