Soluble polymer-supported chemistry is a technology that allows the blending of the benefits of polymer-supported synthesis and solution-phase chemistry. Herein, we describe our recent efforts in this area targeted at exploring the scope of poly(ethylene glycol) (PEG) as the matrix. Specifically we describe the use of PEG as a support for triphenyl phosphine and for the Stille reaction.

It is widely appreciated that an attractive polymer-substrate interaction can slow relaxation in thin supported polymer films and polymer nanocomposites. Recent measurements and simulations on nancomposites have indicated that this slowing of polymer dynamics occurs more strongly near a highly attractive particle surface where a "bound" layer having a much lower mobility can form, strongly infl...

a floating polymer-supported photocatalyst based on polystyrene impregnated with titaniumdioxide particles was developed using a facile solvent-cast method at ambient temperature. the preparedphotocatalysts were characterized by x-ray diffraction, scanning electron microscopy and fourier transforminfrared spectroscopy. the photocatalytic activity of the developed photocatalysts was investigated...

We have studied the effects of grain boundary adhesion and grain size on the ductility of thin metal films well bonded to polymer substrates, using a finite element method. It is shown that the ductility of polymer-supported metal films increases approximately linearly as the grain boundary adhesion increases, and as the grain size decreases. A rule-of-thumb estimate of the ductility of polymer...

The type of prosthetic restoration used in implant rehabilitation greatly contributes to the recovery of masticatory function as well as quality of life in patients. Frameworks for implant-supported prostheses are typically made by casting metal or milling either titanium or zirconia. Recently, nonmetal, polymer-type materials were suggested as framework materials. Polyetherketoneketone (PEKK),...

The complete series of chloro- and bromo-cyclopentadienyl carbonyl complexes [(C5XnH5-n)Fe(CO)2R] (n=1–5, R=Me, Ph) could be prepared from the unsubstituted parent compounds via a sequence lithiations electrophilic halogenations. All four pentahaloyclopentadienyl were studied by X-ray diffraction show an interplay weak intermolecular X…X, X…O X…H interactions.

The Suzuki-Miyaura cross-coupling reaction of 1-aryltriazenes with arylboronic acids catalyzed by a recyclable polymer-supported Pd-NHC complex catalyst has been realized for the first time. The polymer-supported catalyst can be re-used several times still retaining high activity for this transformation. Various aryltriazenes were investigated as electrophilic substrates at room temperature to ...