The direct synthesis of polyaniline-TiO2 nanocomposite coatings on aluminum alloy 3004 (AA3004) surface has been investigated by using the galvanostatic method. The synthesized coatings were characterized by FT-IR, SEM-EDX, SEM and AFM. Optical absorption spectroscopy reveals the formation of the emeraldine oxidation state form of polyaniline-TiO2 nanocomposite. The corros...

The aniline dimer, N-(4-aminophenyl)aniline has been polymerized cleanly under mild conditions to obtain an emeraldine base form of polyaniline using [MeB(3-(Mes)Pz)3]CuCl as the catalyst and H2O2 as the oxidant, while the subsequent acidification of the emeraldine base gives the conducting emeraldine salt form of polyaniline.

A new mechanism for the formation of doped polyaniline is presented. Besides providing suitable structural and spectroscopic parameters, the new mechanism allows for the rationalization of the experimentally observed equilibrium between polaron and bipolaron defects in emeraldine salt. The magnetic behavior and the "metallic island" model for conduction in doped polyaniline are also theoretical...

Polyaniline nanocomposite using metal oxides have wide variety of applicability because its enhanced properties to that pure polyaniline. Here we employed titanium dioxide as the oxide synthesize polyaniline composite (PANi-TiO2 ) through chemical oxidative polymerization in-situ. The obtained PANi-TiO2 is tested for powder X-Ray diffractometry (XRD), & Scanning electron microscopy(SEM).

Akademisk avhandling som med tillsta nd av Kungliga Tekniska Ho gskolan i Stockholm framla gges till offentlig granskning fo r avla ggande av tekniska doktorsexamen fredagen den 10 March kl. Denna avhandling är skyddad enligt upphovsrättslagen. Alla rättigheter förbehålles. To my family God made solids, but surfaces were the work of the devil. Abstract The use of graphene and conductive polyani...

The synthesis of polyaniline- Fe2O3 nanocomposite coating on aluminum Alloy 5052 (AA5052) surface has been investigated by using the galvanostatic method. The anticorrosion performance of polyaniline-Fe2O3 coating was investigated in 3.5% NaCl solution by the open- circuit potential (OCP), Tafel polarization technique and Electrochemical Impedance Spectroscopy (EIS). The corrosion rate of polya...

A straightforward photo-annealing approach was developed for building functional polymer layers on paper. Conducting polyaniline with the ability for photothermal conversion can be readily annealed by near-infrared light. The annealed polymers become both insulating and hydrophobic. Selective photo-annealing produces a functional layer with patterned conductive arrays. This material exhibits re...

A protonated polyaniline-functionalized SBA-15 mesoporous silica nanomaterial (H(+)-PANI/SBA-15) with high surface area and ideal surface properties for the adsorption of anionic dyes is synthesized. Compared with the conventional emeraldine salt of polyaniline (H(+)-PANI), H(+)-PANI/SBA-15 has a significantly higher adsorption capacity for the anionic dye Orange G and is a more effective sorbe...

A polyaniline/In2O3 nanofiber composite based layered surface acoustic wave (SAW) sensor has been developed and investigated towards different gases. Chemical oxidative polymerization of aniline in the presence of finely divided In2O3 was employed to synthesize a polyaniline nanofiber/In2O3 nanoparticle composite. The nanocomposite was deposited onto a layered ZnO/64° YX LiNbO3 SAW transducer. ...