Poly(L-lactic acid) is a linear aliphatic thermoplastic polyester that can be produced from renewable resources. A poly(L-lactic acid)-modified silica stationary phase was newly prepared by amide bond reaction between amino groups on aminopropyl silica and carboxylic acid groups at the end of the poly(L-lactic acid) chain. The poly(L-lactic acid)-silica column was characterized in reversed-phas...

Adhesion of bacteria to biomaterials and the ability of many microorganisms to form biofilms on foreign bodies are well-established as major contributors to the pathogenesis of implant-associated infections. Treatment of bone infection remains problematic, due to the difficulty of systemically administered antibiotics to locally penetrate bone. The current research addresses this issue by focus...

This paper characterizes the fracture toughness of layer-by-layer (LBL) manufactured thin films with elastic polyurethane, a tough polymer, and poly(acrylic acid) as a stiffening agent. A single-edge-notch tension (SENT) specimen is used to study mode I crack propagation as a function of applied loading. Experimental results for the full-field time histories of the strain maps in the fracturing...

Tapioca starch, poly(lactic acid) and Cloisite 30B nanocomposites foams, with clay contents of 1, 3, 5 and 7% (w/w), were prepared by a meltintercalation method. Multiple inputs single output models were developed to predict radial expansion ratio, unit density, bulk compressibility and spring index of the nanocomposite foams. An individual ANFIS model was developed for each mechanical property...

Polymers of lactic and glycolic acid are attractive candidates to fabricate devides to transplant cells and engineer new tissues. These polymers are biocompatible, and exhibit a wide range of erosion times and mechanical properties. This manuscript describes the fabrication and characterization, in vitro and in vivo, of hollow, tubular devices from porous films of various polymers of this famil...

The formation of structures in poly(lactic acid) has been investigated with respect to producing areas of regular, superficial features with dimensions comparable to those of cells or biological macromolecules. Nanoembossing, a novel method of pattern replication in polymers, has been used for the production of features ranging from tens of micrometers, covering areas up to 1 cm(2), down to hun...

Abstract High temperature rubbing is a fast and low‐cost method that can align semi‐crystalline polymers such as poly(lactic acid) (PLA) by application of shear‐force via rotating cylinder covered with microfiber cloth on thin film maintained at high temperature. A multi technique approach uncovers the role thickness PLA structure. Both poly( l ‐lactic (PLLA) stereo‐complex (SC‐PLA) be readily ...

Nanocomposites of poly(lactic acid) with sepiolite needles (5 wt.%) were evaluated in terms the mechanical and biofilm formation properties. The nanocomposite exhibited higher values Young�s modulus tensile strength at break compared to PLA, without detriment percent elongation break. These improvements related high aspect ratio nanoclay, polymer-clay interactions, degree dispersion. growth Pse...