In contrast to simple salts or negatively charged macromolecules, positively charged proteins and peptides including cytochrome c (yeast) and poly-L-lysine are efficiently encapsulated while inducing the formation of polymersomes from polystyrene(140)-b-poly(acrylic acid)(48) (PS(140)-b-PAA(48)).

In this study, poly(N-Isopropylacrylamide) (PNIPAM), poly(acrylamide) (PAAM), poly(acrylic acid) (PAAc), and poly(methacrylic (PMAc) polymers are synthesized by radical polymerization method. The chemical composition surface morphology of the PMAc polymer examined micro-Raman spectroscopy scanning electron microscopy (SEM). electrochemical measurements cyclic voltammetry (CV), chronoamperometry...

Materials and Instruments: All chemicals were used as received without further purification. Hydrogen tetrachloroaurate(III) hydrate (HAuCl4·3H2O), 99.9% (metal basis Au 49%) was purchased from Alfa Aesar; sodium citrate tribasic dihydrate (99.0%), hydroquinone (99.5%) and AgNO3 (99.9999%) were purchased from Sigma-Aldrich; 2-mercaptobenzoimidazole-5-carboxylic acid was purchased from Tokyo Che...

A hierarchically organized architecture in multiple scales was generated from potassium hydrogen phthalate crystals and poly(acrylic acid) based on our novel biomimetic approach with an exquisite association of polymers on crystallization.

Hybrid hollow nanospheres of chitosan-silica templated by chitosan-poly(acrylic acid) nanoparticles are fabricated in a complete aqueous system, which provide a pH-sensitive switch in physiological and sub-cell environments for the release of loaded drug.

Poly(acrylic acid- co-3-azidopropyl acrylate) and poly(acrylic acid- co-propargyl acrylate) have been alternately fabricated into a multilayer via the click reaction. The layer-by-layer deposition was monitored with a quartz crystal microbalance with dissipation (QCM-D) in real time. The response of the multilayer under continuous flow of a bromate-sulfite-ferrocyanide solution with pH oscillat...

Abstract The homophase polymerization of acrylic acid is carried out in a solution poly(butyl acrylate) trithiocarbonate (PBATC) mixed solvent 2-propanol–water. phase diagram the three-component PBATC-2-propanol–water system at 22°C obtained. region compositions semidilute solutions determined. AA 70°C, which with respect to PBATC similar thermodynamic quality θ-solvent 22°, yields narrowly dis...

Bioadhesive polymeric hydrogels capable of firm adhesion to various biological tissues have acquired considerable attention due their significance in medicine and dentistry. Thus far many types bioadhesive been investigated using different polymers such as polyacrylates, poly(ethylene glycol)s, the derivatives polysaccharides proteins, while less has paid polyamphoteric properties cross-linked ...

A novel pH-responsive superabsorbent hydrogel based on gelatin was prepared through crosslinking copolymerization of poly (acrylic acid) and poly (itaconic acid). The copolymerization conditions including monomers, initiator, gelatin and crosslinker concentration, reaction temperature, and neutralization percent were systematically optimized to achieve a hydrogel with swelling capacity as high ...