Titania (TiO2) induced photocatalysis has been widely investigated and applied as a disinfection strategy in many industrial and clinical applications. Reactive oxygen species (ROS), including hydroxyl radicals (•OH), superoxide radicals ( − •2 O ) and hydrogen peroxide (H2O2), generated in the photocatalytic reaction process are considered to be the active components prompting the bactericidal...

Advanced oxidation processes (AOPs) have proved very effective in treatment of the various hazardous organic pollutants in water. The photocatalytic degradation of two azo dyes, monoazo dye Acid Orange 10 (AO10) and diazo dye Acid Red114(AR114) present in wastewater were studied. Homogeneous photocatalytic degradation of the two azo dyes with UV/H2O2 process was investigated. The rates of disap...

Bismuth molybdate thin films were deposited by reactive magnetron co-sputtering from two metallic targets in an argon/oxygen atmosphere, reportedly for the first time. Energy dispersive X-ray spectroscopy (EDX) analysis showed that the ratio of bismuth to molybdenum in the coatings can be effectively controlled by varying the power applied to each target. Deposited coatings were annealed in air...

The sole effect of surface/bulk defects of TiO2 samples on their photocatalytic activity was investigated. Nano-sized anatase and rutile TiO2 were prepared by hydrothermal method and their surface/bulk defects were adjusted simply by calcination at different temperatures, i.e. 400-700 °C. High temperature calcinations induced the growth of crystalline sizes and a decrease in the surface areas, ...

During the last several decades TiO2 photocatalytic oxidation using the molecular oxygen in air has emerged as a promising method for the degradation of recalcitrant organic pollutants and selective transformations of valuable organic chemicals. Despite extensive studies, the mechanisms of these photocatalytic reactions are still poorly understood due to their complexity. In this review, we wil...

Selective photocatalytic aerobic oxidation, which can be conducted under ambient conditions, is of great importance towards achieving sustainable chemistry. However, its practical applications are undermined by several challenges, such as low selectivity, sluggish reaction rates, and the requirement of UV light irradiation. Herein, we report a new concept of synergistic photocatalytic oxidation...

WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution under visible light irradiation was used to determine the...

Nanosized ZrO2 powders with near pure monoclinic, tetragonal, and cubic structures synthesized by various methods were used as catalysts for photocatalytic degradation of methyl orange. The structural and textural properties of the samples were analyzed by X-ray diffraction, Raman spectroscopy, TEM, UV-vis, X-ray photoelectron spectroscopy (XPS), and N2 adsorption measurements. The performance ...

Response surface methodology is a widely used technique for modelling and optimization of the photocatalytic treatment processes of water and wastewater. This methodology not only estimates linear, interaction and quadratic effects of the factors on the response, but also provides a prediction model for the response at the range of the variables studied and the optimum conditions to achieve the...

Ag/Cu2O microstructures with diverse morphologies have been successfully synthesized with different initial reagents of silver nitrate (AgNO3) by a facile one-step solvothermal method. Their structural and morphological characteristics were carefully investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), and the experime...