The uncoupler desaspidin is labile in the presence of oxidants at alkaline pH values. It also undergoes chlorophyll-sensitized photooxidation at a more acid pH. The products of the oxidation appear to have negligible activity in inhibiting electron transfer and photophosphorylation.Failure of desaspidin to uncouple in the presence of oxidants used as cofactors of noncyclic electron flow is pres...

Heart lipoamide dehydrogenase, liver alcohol dehydrogenase and egg-white lysozyme are photo-oxidized in the presence of various dye sensitizers. The photodynamic process is preceded by the binding between the enzyme and the sensitizers. Among the commonly used dyes, halogenated xanthines and thiazine are effective sensitizers for the photo-inactivation of these three enzymes. Histidine residues...

Rapid formation of isoprene photo-oxidation products observed in Amazonia T. Karl, A. Guenther, A. Turnipseed, P. Artaxo, and S. Martin National Center for Atmospheric Research, 1850 Table Mesa Dr, Boulder, 80301, CO, USA Instituto de Fisica, Universidade de Sao Paulo, Sao Paulo, Brazil School of Engineering and Applied Sciences & Department of Earth and Planetary Sciences, Harvard University, ...

We report a mechanistic study of the catalytic effect of Ni(OH)2 on hematite nanowires for photoelectrochemical water oxidation. Ni compounds have been shown to be good catalysts for electrochemical and photoelectrochemical water oxidation. While we also observed improved photocurrents for Ni-catalyst decorated hematite photoanodes, we found that the photocurrents decay rapidly, indicating the ...

1. l-Glutamate decarboxylase (EC 4.1.1.15) from Clostridium perfringens was inactivated by exposure to visible light at pH6.2. 2. Inactivation does not occur at pH4.6 or in the absence of bound pyridoxal phosphate. 3. On prolonged photo-oxidation six histidine residues per molecule of enzyme were destroyed. 4. The loss of six cysteine residues per molecule occurred both in irradiated samples an...

Photo-oxidation (in the presence of eosin Y as a sensitizer) of isohemagglutinating sera destroyed their agglutinating activity gradually, but did not seem to convert any of the agglutinins studied into inhibiting ("incomplete" or "blocking") antibody.

Several homogeneous photo-based advanced oxidation processes-namely photolysis, photo-oxidation, and photo-Fenton oxidation—were investigated for the elimination of ibuprofen in water. The effects several operating parameters, such as lamp type (low or medium pressure mercury, xenon-arc), concentration hydrogen peroxide (0.5 to 7 times stoichiometric amount required mineralization), Fenton reag...

Organic pollution is the term used when large quantities of organic compounds are found in waste water. It originates from domestic sewage, urban run-off; industrial effluents and agriculture wastewater. Water shortage and water quality are the main issues in the global water crisis. As the population increases, there is ever growing demand on water resources. Wastewater with organic pollutants...

the efficiency of oxidation processes, enzymatic treatment, and combined enzymatic/chemical sequences on color remediation of cmp pulp mill effluent was investigated. two kinds of fungal enzymes; laccase (ec: 1.10.3.2) from terametes versicolor and versatile peroxidase (ec: 1.11.1.7) from bjerkandera adusta were chosen and applied. also, the effect of external mediator on the enzyme based degra...

in recent years, the effects of heterogeneous catalysts for the oxidation of organic and inorganic pollutants in industrial wastewaters are spread. traditionally, these reactions are usually carried out using suspensions of photo-catalysts such as tio2. a chemical method including ticl4, al(no3)3, ethanol amine, ethyl acetoacetate and aqueous ammonia were used for the fabrication of tio2-al2o3 ...