Since the pioneering efforts of Duwez and co-workers in 1965, when a solid amorphous phase palladium-silicon (a-PdSi) was obtained vicinity eutectic concentration, much work has been done. However, some points related to atomic structures remain be systematized. In this work, 8 Pd100-cSic alloys (c = 2.5, 5, 10, 13.34, 15, 17.5, 20, 22 at%) are generated by molecular dynamics ab initio simulati...