persistent organic pollutants (pops) have widely aroused public concern due to their ubiquity,environmental persistence, long-range transportability, bioaccumulation capacities and potentially adverse effectson living organisms. dakar is located in the industrial zone of senegal (80% of industrial activities) and inhabits25% of senegalese population leading to an ideal sink of these persistent ...

Polycyclic aromatic hydrocarbons (PAHs) are abundant in many regions of the Universe, representing a major reservoir for cosmic carbon. However, their formation pathways cold space remain elusive. Recent astronomical detections show that current astrochemical models drastically underestimate abundance molecules and suggest additional such as ion–molecule reactions need to be considered. Here we...

The mid-IR spectra of six large, irregular PAHs with formulae (C84H24 – C120H36) have been computed using Density Functional Theory (DFT). Trends in the dominant band positions and intensities are compared to those of large, compact PAHs as a function of geometry, size and charge. Irregular edge moieties that are common in terrestrial PAHs, such as bay regions and rings with quartet hydrogens, ...

the major sources of pahs are anthropogenic. these may be generated by pyrolytic and petrogenic processes. low molecular weight pahs come into the aquatic system through the accidentally leakage of oil spills. incomplete combustion at high temperature will release high molecular weight pahs by products of pyrolytic processes. the methods for assigning sources of pahs include paired isomeric rat...

Effect of norfloxacin (Nor) on the sorption of 1,3-dinitrobenzene (1,3-DNB), and PAHs (naphthalene (NAPH), phenanthrene (PHEN) and pyrene (PYR)) to K(+)-montmorillonite was studied. Nor suppressed 1,3-DNB sorption due to their competition for the same sorption sites. 1,3-DNB was sorbed on K(+)-montmorillonite surface via cation-polar interaction and n-π electron donor-acceptor interaction. Nor ...

Novosphingobium pentaromativorans US6-1, a marine bacterium isolated from muddy sediments of Ulsan Bay, Republic of Korea, was previously shown to be capable of degrading multiple polycyclic aromatic hydrocarbons (PAHs). In order to gain insight into the characteristics of PAHs degradation, a proteome analysis of N. pentaromativorans US6-1 exposed to phenanthrene, pyrene, and benzo[a]pyrene was...

A comparative study was conducted to elucidate the mechanism underlying the separation of poly-aromatic-hydrocarbons (PAHs) and related compounds thereof on a column packed with silica gels modified with Ni(II)- or Cu(II)-phthalocyanine derivatives (PCS) (Ni- or Cu-PCS(D) column) and commercially available PYE and NPE columns with a non-polar eluent, such as n-hexane. It has been revealed that ...

Abstract This study assesses the contribution of neutral polycyclic aromatic hydrocarbons (PAHs) and hydrogenated PAHs (H n -PAHs) in H 2 O-ices to 3 μ m 5–8 regions infrared absorption spectrum Young Stellar Object, Mon R2 IRS 3, Taurus dense cloud direction Elias 16. We compare astronomical spectra previously published laboratory data matrix-isolated -PAHs O-ices. For molecules this study, ba...