We report femtosecond visible pump, midinfrared probe, spectrally integrated experiments resolving the dynamics of CO in myoglobin upon photodissociation. Our results show a progressive change in absorption strength of the CO vibrational transition during its transfer from the heme to the docking site, whereas the vibrational frequency change is faster than our time resolution. A phenomenologic...

The 4d relative photoabsorption cross section of cesium has been observed to change dramatically in appearance along the isonuclear sequence Cs through Cs. In each case, discrete structure is observed below threshold and for Cs through Cs, a giant dipole 4d→« f resonance is also present above threshold. Between Cs and Cs, there is a striking change, with much of the oscillator strength availabl...

We report on the optical properties of the hole-doped manganites Nd0.7Sr0.3MnO3, La0.7Ca0.3MnO3, and La0.7Sr0.3MnO3. The low-energy optical conductivity in the paramagnetic-insulating state of these materials is characterized by a broad maximum near 1 eV. This feature shifts to lower energy and grows in optical oscillator strength as the temperature is lowered into the ferromagnetic state. It r...

Linear and nonlinear refractive index, Abbe number, electronic energy gap and oscillator strength are reported for a new series of (Mg, Ba)F2-based fluorophosphates glasses (MBBA system) doped with rare earth dopants (Er , Nd) in the concentration range of 6.67x10 2.86x10 (ions/cm) and 2.5x10 1.25x10 (ions/cm), respectively. The linear refractive index is found to increase with increasing dopan...

We present calculations for the oscillator strength of the recombination of excitons bound to phosphorus donors in silicon. We show that the direct recombination of the bound exciton cannot account for the experimentally measured oscillator strength of the no-phonon line. Instead, the recombination process is assisted by an Umklapp process of the donor electron state. We make use of the empiric...

Intersubband optical transitions at short wavelengths in strain-compensated In0.70Ga0.30As—AlAs double quantum wells are investigated by means of mid-infrared absorption. Trade-offs between achieving a high transition energy and a large oscillator strength of the two highest-energy intersubband transitions using our strain-compensation approach are analyzed as a function of the widths of the tw...

An expression of unexpected simplicity is derived for the shift in optical transition energies of solute molecules in nonpolar solvents. The expression reveals a new spectroscopic rule that says: The higher the excited state of the solute, the larger the solvatochromic red shift. A puzzle formulated >50 years ago by Bayliss is solved. Bayliss, based on arguments from classical physics, assumed ...

Martin Gouterman first proposed the four-orbital model in the 1960s to explain the absorption spectra of porphyrins [17, . According to this theory, the absorption bands in porphyrin systems arise from transitions between two HOMOs and two LUMOs, and it is the identities of the metal center and the substituents on the ring that affect the relative energies of these transitions. The HOMOs were c...

We present measurements of the spectra of electrons with energy between 0.6 and 2.25 keV elastically and inelastically scattered from Ar and Ne over large angles (from 3◦ to 135◦). The intensity of the first loss feature [np → (n+ 1)s], relative to that of the elastic peak, was determined and compared with the results of relativistic distorted-wave calculations (for the energy loss part) and a ...