Topanol A is a phenolic antioxidant additive, which is used in storage tanks for jet fuels produced in the petroleum refineries throughout the country. Topanol A mostly consists of 2,6-di-t-butylphenol. The conventional methods for the preparation of this compound involve ortho-alkylation of phenol using 2-methylpropene (isobutylene) as the alkylating agent. The compound has been prepared by or...

introduction superficial x-ray therapy is one of the most important treatment methods in radiotherapy especially in the treatment of superficial skin lesions (up to 300 kvp). quality of the x-ray beam that can be expressed by half-value layer (hvl), are important indices for this type of treatment effective energy of photon and homogeneity coefficient (hc). materials and methods the hc of the s...

Hydrogen is an unusual substance in that its molecule exists in two forms, known as ortho and para, with markedly different properties. Energy level of the ortho molecule is higher than para, therefore, the latter is employed for industrial purposes. Consequently, for a high  conversion of  ortho to para hydrogen a catalyst reactor must be employed.  Therefore, one of  the main obj...

The use of methanesulfonic acid as a Brønsted acid for direct ortho-acylation of phenols and naphthols proves to be a convenient, more general and direct route to various hydroxyaryl ketones. The route is regioselective, leading to ortho C-acylated products in satisfactory to high yields in most cases. The solvent free reactions described below exhibited environmentally benign in terms of faste...

The first regioselective oxidative coupling of 2-hydroxycarbazoles is described. With a vanadium catalyst and oxygen as the terminal oxidant, dimers with an ortho-ortho' coupling pattern were obtained with high selectivity. Further oxidation led to ortho'-ortho' coupling to generate a tetramer, which provided insight that the atropisomerization barriers of the unsymmetrical biaryl bonds are muc...

The ortho to para conversion of water ion, H2O(+), due to the interaction between the magnetic moments of the unpaired electron and protons has been theoretically studied to calculate the spontaneous emission lifetime between the ortho- and para-levels. The electron spin-nuclear spin interaction term, Tab(SaΔIb + SbΔIa) mixes ortho (I = 1) and para (I = 0) levels to cause the "forbidden" ortho ...

A highly toxic nerve agent, tabun, can inhibit acetylcholinesterase (AChE) at cholinergic sites, which leads to serious cardiovascular complications, respiratory compromise and death. We have examined the structural features of the tabun-conjugated AChE complex with an oxime reactivator, Ortho-7, to provide a strategy for designing new and efficient reactivators. Mutation of mAChE within the ch...

We demonstrate an efficient enantioselective oxidation of secondary alcohols catalyzed by Mn(III)-salen complex using N-bromosuccinimide (NBS) as the oxidant. The new protocol is very efficient for the oxidative kinetic resolution of a variety of secondary alcohols, including ortho-substituted benzylic alcohols.