The MODAR process uses supercritical water, heated above 374OC and pressurized above 220 atm, as a medium for the rapid and complete oxidation of organic compounds to carbon dioxide, water and inorganic salts. The destruction efficiencies achieved exceed 99.99% for a wide range of compounds including chlorinated solvents and PCB’s. The exothermic oxidation reaction produces sufficient energy to...

Quasi-two-dimensional crystalline organic metals and superconductors are very flexible systems in the study of many-body effects and unusual mechanisms for superconductivity [1, 2, 3, 4, 5, 6, 7]. Their “soft” lattices enable one to use relatively low pressures to tune the same material through a variety of low-temperature groundstates, for example from Mott insulator via intermingled antiferro...

The first luminescent Bi-Cd-organic framework, Bi2Cd(2,6-pdc)4(H2O)2·H2O (2,6-H2pdc = pyridine-2,6-dicarboxylate), has been synthesized by using bismuth (Bi) oxides and cadmium (Cd) salts as metal sources under hydrothermal conditions. Tunable and white light luminescence was obtained through the doping of different Ln(3+) ions into the Bi-Cd-organic framework.

The formation of layer-like FAU-type zeolites was facilitated in the absence of any organic template. Instead, the addition of simple inorganic salts turned out to be an effective and easy to handle alternative to organic additives to induce morphological and even structural changes during zeolite crystallisation.

Imidazolium salts are privileged compounds in organic chemistry, and have valuable biological properties. Recent studies show that symmetric imidazolium salts with bulky moieties can display antiparasitic activity against T. cruzi. After developing a facile methodology for the synthesis of tetrasubstituted imidazolium salts from propargylamines and isocyanides, we screened a small library of th...

Reactions of 5-(9H-carbazol-9-yl)-isophthalate and metal salts provide laminar metal organic frameworks (MOFs) wherein interlayer interactions of the pendant carbazoles engender extended aromatic stacks or non-stacked structures with enhanced solid-state emission. These studies emphasize that MOFs serve as versatile supramolecular platforms to direct the aggregation and electroptical behaviours...

This communication demonstrates the preparation, isolation, and full characterization of superelectrophilic salts based on amidine dications in organic solvent, as their triflate salts. These dications are highly activated toward regiospecific reaction with hydrogen gas under mild conditions in the presence of a metal catalyst (Pd/C), mimicking the behavior of the natural substrate, N(5),N(10)-...

The growth of Pseudomonas fluorescens (ATCC 11150) on sodium maleate was observed, and the composition of the media was monitored in batch culture. Utilization of the maleate as the sole organic carbon source proceeded by stepwise conversion to fumarate and then to malate. Respiration rates of P. fluorescens on maleate, mixtures of maleate and fumarate salts, and mixtures of maleate and malate ...

Sulfones feature prominently in biologically active molecules and are key functional groups for organic synthesis. We report a mild, photoredox-catalyzed reaction for sulfonylation of aniline derivatives with sulfinate salts, and demonstrate the utility of the method by the late-stage functionalization of drugs. Key features of the method are the straightforward generation of sulfonyl radicals ...

Select triarylsulfonium salts constitute ionic liquids with outstanding long-term, high-temperature aerobic stability (no mass loss in 90 days at 300 C in air), making them among the most thermally stable organic materials known. A detailed analysis of their thermophysical properties reveals that lowering melting points in these salts by increasing ion size or lowering ion symmetry cannot be as...