background: the presence of heavy metals in aquatic and terrestrial ecosystems causes harmful effects to living organisms in the environment. this research aimed to determine the potential of activated pumice stone (aps) as a sorbent for the removal of cd, cu, and zn from wastewater. methods: this research was conducted during 2013 on a laboratory scale. the study was performed using batch expe...

introduction: discharging of industrial colored wastewaters especially into aqueous environments can cause adverse effects on aquatic life due to their toxic natures. in this study, montmorillonite modified by hexadecyltrimethyl ammonium bromide (hdtma-mt) was used for the adsorption of methylene blue (mb). materials and methods: the influence of surfactant loading rate, contact time, ph, adsor...

In this study, an infrared (IR) hollow waveguide sampler was developed to detect organic compounds in aqueous samples with sample volumes less than 50 microL. This sampler was prepared by coating a thin hydrophobic film inside the IR hollow waveguide. After injecting a certain amount of aqueous solution, organic compounds could be absorbed into the hydrophobic film by partitions. By removing th...

Amphiphilic anthracene derivatives showed solvent-polarity-dependent fluorescence. Monomer emission and aggregation-induced emission (AIE) were observed in polar and non-polar organic solvents, respectively. AIE became predominant in aqueous solution in the case of hexafluorophosphate as a counter anion.

The removal mechanisms of three hormone mimicking organic compounds by nanofiltration (NF) membranes have been examined. Two NF membranes having different pore sizes were used in laboratory-scale nanofiltration experiments with feed solutions spiked with a hormone mimicking compound—nonylphenol, tertbutylphenol, or bisphenol A. Retention of the compounds was determined at various solution chemi...

Biological activity of drugs and other organic compounds is determined by their solubilities in water or any other solvent or solution. Several methodologies to compute the solubilities of organic compounds have been devised, however most of them are bound to aqueous solutions, and many times the methodology works for a limited number of compounds. Furthermore, those methodologies state very li...

Generator columns packed with a solid support and loaded with a liquid organic phase make it possible to rapidly and conveniently equilibrate water with the organic phase. By coupling the generator column to an extractor column for high pressure liquid chromatographic analysis of the aqueous solution, errors from surface adsorption and loss to the atmosphere are avoided. Using this method, the ...

The water-immiscible ionic liquid, [C4MIM][PF6], is a solvent medium that allows complete transfer of gold nanoparticles from an aqueous phase into an organic phase. Both spherical and rod-shaped gold nanoparticles are efficiently transferred from an aqueous solution into the organic phase without requiring the use of thiols. The sizes and shapes of the gold nanoparticles were preserved during ...

Spray freeze-drying (SFD) technique using four-fluid nozzle (4N), which is a novel particle design technique previously developed by authors, has been further developed to expand its application in pharmaceutical industry. The organic solvent was utilized as a spray solvent to dissolve the poorly soluble drug instead of conventional aqueous solution. Acetonitrile solution of the drug and aqueou...

In this work, we have evaluated how well the general assisted model building with energy refinement (AMBER) force field performs in studying the dynamic properties of liquids. Diffusion coefficients (D) have been predicted for 17 solvents, five organic compounds in aqueous solutions, four proteins in aqueous solutions, and nine organic compounds in nonaqueous solutions. An efficient sampling st...