A new strategy for Rh(I)-catalyzed [2+2+2] cycloadditions of 1,6-diynes with potassium (Z)-(2-bromovinyl)trifluoroborate as the third two-atom unit has been realized, which provides a facile entry to polysubstituented benzene derivatives.

Hexa-substituted benzene derivatives show larger two-photon cross sections than the corresponding dipolar counterparts and the largest values of delta(max) = 2000 GM and delta(max)/MW = 2.25 GM g(-1) have been obtained with a compound having C[triple bond]C and C=C bonds in the conjugation bridge.

We have successfully developed a new synthetic approach to modulate the electrostatic potentials of metallocavitands and thus their selective recognition towards substituted benzene derivatives via integrating two metal cations of different electronegativity into a self-assembled system.

Derivatives are innovative financial instruments in the 21st century to help market participants mitigating risk. Commodity derivatives not new world, but reentered with face into fray. In India, introduced at first on index and followed by securities commodities phase wise for betterment of markets price discovery. The present study explores association trend between Spot Futures Market India ...

Crude oils and source rocks from the northern and offshore Niger Delta basin, Nigeria, have been characterized by gas chromatography-mass spectrometry in terms of their origin and thermal maturity based on the distribution of chrysene and its derivatives. The crude oils and source rocks were characterized by the dominance of chrysene over benzo[a]anthracene. 3-methylchrysene predominated over o...

b a ckground: application of plant derivatives have been suggested as alternative sources for mosquito control. m ethods: the root essential oil and methanol extract of c ionura erecta (l.) griseb was tested under laboratory conditions for larvicidal and skin repelleny activities against anopheles stephensi . the chemical compositions of essential oils were analyzed using gas chromatography- ma...

In this study, we combined different physico-chemical methods to show the effect of overheating on the quality of golden fry cooking oil. Those methods include spectroscopic methods such us 1H-NMR, 13C-NMR and FTIR. Results showed that both overheating and excessive reuse of golden fry cooking oil seriously affected its quality by increasing its density, viscosity and different indexes like ref...

The antimicrobial properties of essential oils, terpineol, and orange oil, in particular, varied according to the type of bacteria tested. Terpineol and other terpeneless fractions of citrus oils appeared to have greater inhibitory effect on food-borne bacteria than the other citrus oils or derivatives. Gram-positive bacteria were, in general, more sensitive to essential oils than gram-negative...

BACKGROUND Application of plant derivatives have been suggested as alternative sources for mosquito control. METHODS The root essential oil and methanol extract of Cionura erecta (L.) Griseb was tested under laboratory conditions for larvicidal and skin repelleny activities against Anopheles stephensi. The chemical compositions of essential oils were analyzed using gas chromatography- mass sp...

Till recently the mainstay in the treatment of leprosy were Hydnocarpus (Chaulmoogra) Oil and its derivatives. The foundations of chemotherapy of leprosy can be said to have been laid early in this century with the isolation of hydnocarpic and chaulmoogric acids, believed to be the active principles of the oil, and the preparation of sodium salts of these acids. The introduction of sulphone dru...