The Microtox toxicity and Oxygen Uptake Rate (OUR) inhibition tests were conducted to monitor the variation of toxicity during ozonation of 2-chlorophenol (2-CP), 3-chlorophenol (3-CP) and 4-chlorophenol (4-CP) under neutral conditions. The results revealed that the oxidized 2-CP solution exhibited new toxicity to pure bacteria and mixed microorganisms in the early stage of ozonation. The large...

Partially-puri®ed extracellular laccase of Coriolus versicolor transformed chlorophenols in the following order: 2,4,6trichlorophenol > 2,6-dichlorophenol > 2,4-dichlorophenol, 2-chlorophenol > 2,3-dichlorophenol. On the other hand, 3and 4chlorophenols, 2,5-, 3,4and 3,5-dichlorophenols, 2,4,5-trichlorophenol and pentachlorophenol were recalcitrant to the laccase. Sinapinic acid, a naturally-occ...

Excilamps are new UV sources with great potential for application in wastewater treatment. In the present work, a XeBr excilamp emitting radiation at 283 nm has been used for the photodegradation of 4-chlorophenol within a range of concentrations from 50 to 500 mg L. Total removal of 4-chlorophenol was achieved for all concentrations assayed. The two main photoproduct intermediates formed along...

Heterogeneous Fe-Mn/sepiolite catalysts were prepared by the coprecipitation method, followed by heat treatment. The catalysts were characterized by several techniques; analysis by X-ray fluorescence (XRF) and scanning electron microscopy (SEM) confirmed the existence of fine Fe and Mn particles in the catalysts. Compared to natural sepiolite, the specific surface area of the Fe-Mn/sepiolite ca...

A novel indirect electrochemical protocol for the electroanalytical detection of phenols is presented for the first time. This methodology is demonstrated with the indirect determination of the target analytes phenol, 2-chlorophenol, 4-chlorophenol and 2,4-dichlorophenol through an electrochemically adapted optical protocol. This electrochemical adaptation allows the determination of the above ...

The degradation of 2-chlorophenol (2-CP) by persulfate was investigated. The kinetics of persulfate oxidation of 2-chlorophenol in aqueous solutions at various pH, oxidant concentration, temperature, Fe2+ and Cu2+ ions content was studied. Maximum of 2-CP degradation occurred at pH 8. The oxidation rate of 2-CP increased with increasing the persulfate molar excess. The degradation process was s...

The removal efficiency of 4-chlorophenol with different advanced oxidation processes have been studied. Oxidation experiments were carried out using two 4-chlorophenol concentrations: 100 mg L and 250 mg L and UV generated from a KrCl excilamp with (molar ratio H2O2: 4-chlorophenol = 25:1) and without H2O2, and, with Fenton process (molar ratio H2O2:4chlorophenol of 25:1 and Fe concentration of...

OBJECTIVE To isolate, incubate, and identify 4-chlorophenol-degrading complex bacteria, determine the tolerance of these bacteria to phenolic derivatives and study their synergetic metabolism as well as the aboriginal micrpbes and co-metabolic degradation of mixed chlorophenols in river water. METHODS Microbial community of complex bacteria was identified by plate culture observation techniqu...

approved: LRedacted for Privacy Kenneth J. Williamson Chlorinated phenols are toxic compounds and often released into natural environments from improper disposal or non-point sources. One important factor in assessing the environmental fate and transport is the rates of microbial degradation in soils and natural waters. In this study, eight chlorophenols (4-chlorophenol (4-CP), 2,4-dichlorophen...

To evaluate the association of chlorophenol exposure with soft tissue sarcoma risk independent of phenoxyherbicide exposure, the authors analyzed data from the Selected Cancers Study, a population-based case-control study that included 295 male soft tissue sarcoma cases, aged 32-60 years, from eight population-based cancer registries and 1,908 male controls. Chlorophenol exposure was assigned u...