Unlike the more established lithium-ion based energy storage chemistries, the complex intercalation chemistry of multivalent cations in a host lattice is not well understood, especially the relationship between the intercalating species solution chemistry and the prevalence and type of side reactions. Among multivalent metals, a promising model system can be based on nonaqueous Zn ion chemistry...

In this work, a facile and highly efficient on-line concentration strategy based on a coupling of field enhanced sample injection (FESI) and sweeping was developed for the determination of trace enantiomers (propranolol, PL) by nonaqueous capillary electrophoresis (NACE). In this FESI-sweeping method, the use of a sample of high acidity and low conductivity (pH* = 2.5, 4.0 μS cm(-1)) allowed fo...

Low-temperature and ambient-temperature nonaqueous stacking techniques in capillary electrophoresis (CE) are described for the first time. A low-temperature bath was used to control the temperature from ambient to subzero degrees, by which a novel hyphenated method, low-temperature bath-nonaqueous capillary electrophoresis stacking (LTB-NACE stacking) is demonstrated. 3,4-Methylenedioxymethamph...

Interfacial activation-based molecular (bio)-imprinting (IAMI) has been developed to rationally improve the performance of lipolytic enzymes in nonaqueous environments. The strategy combinedly exploits (i) the known dramatic enhancement of the protein conformational rigidity in a water-restricted milieu and (ii) the reported conformational changes associated with the activation of these enzymes...

Abstract Nonaqueous sodium- and lithium-oxygen batteries are of interest because their high theoretical specific energies relative to state-of-the-art Li-ion batteries. However, several challenges limit rechargeability, including instability the carbon electrode electrolyte with reactive oxygen species formed during cycling. This work investigates strategies improve cycling efficiency Na–O 2 sy...

An annual increase of CO2 concentrations in the atmosphere causes global environmental problems, addressed by systematic research to develop effective technologies for capturing and utilizing carbon dioxide. Electrochemical catalytic reduction is one directions conversion into valuable chemicals fuels. The electrochemical at catalytically active electrodes aqueous solutions most studied. Howeve...

This paper (SPE 113936) was accepted for presentation at the SPE/DOE Symposium on Improved Oil Recovery, Tulsa, 20–23 April 2008, and revised for publication. Original manuscript received for review 20 February 2008. Revised manuscript received for review 23 March 2009. Paper peer approved 8 September 2009. Summary Design of an alkaline/surfactant/polymer (ASP) process requires knowledge of the...