The denitrifying fungus Cylindrocarpon tonkinense was thought to be able to denitrify only nitrite (NO2-) but not nitrate (NO3-) to form nitrous oxide (N2O). Here we found, however, that C. tonkinense can denitrify NO3- under certain conditions. Presence of ammonium (NH3+) in addition to NO3- and the use of a fermentable sugar as an electron donor were key conditions for inducing the denitrifyi...

We determined relative nitrate–nitrogen (NO3-N) loss rates in 100 north–mid-European lakes from late spring to summer by using the exponential function N2 5 N1e2 2 t2), where N1 and N2 are NO3-N concentrations at the beginning (t1) and the end (t2) of the time interval, respectively, and k is the specific NO3-N loss rate. We found that k decreased with increasing lake depth. Adjusting k to the ...

Mononuclear mixed-anions Mn complex of TPAMn(η-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)amine, has been synthesized and characterized. The neutral TPAMn(η-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate...

Riparian ecosystems, through their unique position in the agricultural landscape and ability to influence nutrient cycles, can potentially reduce NO3 loading to surface and ground waters. The purpose of this study was to determine the fate of NO3 in shallow groundwater moving along a lateral flowpath from a grass seed cropping system through an undisturbed mixed-species herbaceous riparian area...

The natural removal of NO3 by denitrification within riparian zones of streams and rivers is an area of considerable interest owing to its potential to minimize the impacts of excess anthropogenic loadings. In this study we utilize natural variations in stable N isotopic compositions of NO3 and NH4 within a transect of shallow wells extending 4 m inland from Smith Creek, a southwestern Michigan...

Most plants use nitrate (NO3-) as their major nitrogen (N) source. The NO3- uptake capacity of a plant is determined by three interdependent factors that are sensitive to NO3- availability: (i) the functional properties of the transporters in roots that contribute to the acquisition of NO3- from the external medium, (ii) the density of functional transporters at the plasma membrane of root cell...

Elevated levels of nitric oxide (NO2-/NO3-) were detected in the serum of mice 3-7 days after priming with Corynebacterium parvum (Propionibacterium acnes). The serum NO2-/NO3- response was completely inhibited when C. parvum-primed (C. parrum) mice were treated with N(G)-monomethyl-L-arginine (L-NMMA) or aminoguanidine (AG) on days 6 and 7 post priming. The response was also inhibited when the...

[1] Nitrate (NO3 ) movement was studied using a combination of isotopic, chemical, and hydrometric data within the 135 ha Archer Creek watershed in the Adirondack Mountains of New York from January 1995 to December 1996. This research was conducted to identify sources of stream water NO3 and the mechanisms that deliver NO3 to the stream to test two hypotheses: (1) Soil water NO3 concentrations ...

Initial attempts to make [Ni(H2O)2(15-crown-5)](NO3)2, i.e. to insert the Ni2+ ion into the 15-crown-5 macrocycle, gave the mono- (two polymorphs) and dihydrate of a co-crystal of[Ni(H2O)6](NO3)2 and 15-crown-5 (1,4,7,10,13-pentaoxacyclopentadecane=15C5). Synthetic routes designed to restrict the water available to the Ni2+ cation gave three additional compounds, [Ni(H2O)6](NO3)2-trans-[Ni(H2O)...

Influence of acetate-C/NO3(-)-N/S(2-) ratio to the functional microbial community during the denitrifying sulfide removal process is poorly understood. Here, phylogenetic and functional bacterial community for elemental sulfur (S(0)) recovery and nitrate (NO3(-)) removal were investigated with the switched S(2-)/NO3(-) molar ratio ranged from 5/2 to 5/9. Optimized S(2-)/NO3(-) ratio was evaluat...