نتایج جستجو برای: nitrogen inversion barrier

تعداد نتایج: 251299  

2008
K. Hagino N. Takigawa

We discuss the effects of fast nuclear excitations on heavy-ion fusion reactions at energies near and below the Coulomb barrier. Using the fusion of two 40 Ca nuclei as an example and the inversion method, we show that the mass renormalization induced by fast nuclear excitations leads to a large surface diffuseness in the effective potential for heavy-ion fusion reactions.

Journal: :Journal of biomolecular NMR 2003
Eriks Kupce Ray Freeman

Three-dimensional HNCO and HNCA subspectra from a small protein (agitoxin, 4 kDa, enriched in carbon-13 and nitrogen-15), have been obtained by direct frequency-domain excitation of selected carbon and nitrogen sites. This new technique applies an array of several simultaneous soft radiofrequency spin-inversion pulses, encoded (on or off) according to nested Hadamard matrices, and the resulting...

1997
Jay H. Brown

N-Allyl-N-methyl-2-aminopropane (AMAP) is a relatively simple tertiary amine that has a chiral center at the pyramidal nitrogen. Racemization occurs by inversion-rotation at nitrogen. For each AMAP enantiomer, conformational exchanges occur via isolated rotation about carbon-nitrogen and carbon-carbon bonds. The 1H and 13C{1H} dynamic NMR (DNMR) spectra of AMAP show a higher temperature decoale...

2015
Yi Zhao

has been developing III-nitride double heterostructures (DHs) with indium gallium nitride (InGaN) channels with a view to high-electron-mobility transistors (HEMTs) [Yi Zhao et al, Appl. Phys. Lett., vol105, p223511, 2014]. The resulting structures boast the highest reported mobility for InGaN channels and superior transport at high temperature, according to the research team. Nitride semicondu...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه رازی - پژوهشکده فنی و مهندسی 1388

asymmetric polyethersulfone (pes) microfiltration flat sheet membranes were composed by the phase inversion method (pim) and were used as supports. composite membranes were fabricated by coating silicone rubber as selective layer. effect of different concentrations of pes and pdms and different solvent such as nmp, dmf and dms effects as pes solvents and support thickness and different coagulat...

2007
S. G. Kou

Discrete barrier and lookback options are among the most popular path-dependent options in markets. However, due to the discrete monitoring policy almost no analytical solutions are available for them. We shall focus on the following methods for discrete barrier and lookback option prices: (1) Broadie–Yamamoto method based on fast Gaussian transforms. (2) Feng–Linetsky method based on Hilbert t...

Journal: :Angewandte Chemie 2003
Michael A T Maughan Ieuan G Davies Timothy D W Claridge Steve Courtney Phil Hay Benjamin G Davis

Although amine nitrogen atoms are potential stereogenic centers, their configurational lability arising from lone-pair inversion has typically prevented their utility in synthesis.NHalogenation can dramatically slow lone-pair inversion and therefore raise the temperature at which the configurational lability ceases. We therefore considered that if a suitable system could be found, N-chloramines...

2001
Philippe Y. Ayala H. Bernhard Schlegel

The insertion of SiHs into Fz has been studied with MP2, CCD, CISD and QCISD. For fluorine approaching syn to the silicon lone pair, the complex is 2.5 kcal/mol below reactants and the insertion barrier is 0.5 kcal/mol above reactants at QCISD/63 1 G*; for the anti approach, there is no barrier (only a broad plateau) and insertion proceeds with inversion at silicon. With RQCISD, both pathways g...

1997
Antoon Pelsser

Double barrier options have become popular instruments in derivative markets. Several papers have already analysed double knock-out call and put options using di erent methods. In a recent paper, Geman and Yor (1996) derive expressions for the Laplace transform of the double barrrier option price. However, they have to resort to numerical inversion of the Laplace transform to obtain option pric...

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