The structures of the 1:1 co-crystalline adduct C8H6BrN3S·C7H5NO4, (I), and the salt C8H7BrN3S(+)·C7H3N2O7 (-), (II), obtained from the inter-action of 5-(4-bromo-phen-yl)-1,3,4-thia-diazol-2-amine with 4-nitro-benzoic acid and 3,5-di-nitro-salicylic acid, respectively, have been determined. The primary inter-species association in both (I) and (II) is through duplex R (2) 2(8) (N-H⋯O/O-H⋯O) or...

Abstract Several species of thymus have therapeutic properties, so they are used in traditional medicine. In this work was carried out to synthesize Thymus vulgalis silver nanoparticles (TSNPS) and evaluate antioxidant antimicrobial activities TSNPS T. essential oil extract (TEOE). The oils analyzed by GC-MS were characterized. Major compounds phenol, 2 methyl 5 (1 methylethyle) (CAS), thymol 1...

In this work, we report the synthesis of silver decamolybdate, Ag6Mo10O33, nanostructure by a simple mechanohemical process followed by calcination treatment using acetamide as driving agent. Morphological study by scanning electron microscopy (SEM) images revealed bundles of rods grown closely together with an average diameter of 92 nm for Ag6Mo10O33 sample. Ni-substituted Ag6Mo10O33 compound ...

The anhydrous salts of the Lewis base 1,8-di-aza-bicyclo-[5.4.0]undec-7-ene (DBU) with 4-amino-benzoic acid [1-aza-8-azoniabi-cyclo-[5.4.0]undec-7-ene 4-amino-benzoate, C9H17N2 (+)·C7H6NO2 (-) (I)], 3,5-di-nitro-benzoic acid [1-aza-8-azoniabi-cyclo-[5.4.0]undec-7-ene 3,5-di-nitro-benzoate, C9H17N2 (+)·C7H3N2O6 (-), (II)] and 3,5-di-nitro-salicylic acid (DNSA) [1-aza-8-azoniabi-cyclo-[5.4.0]unde...

Except two F atoms of the -CF(3) group, the title compound, C(14)H(8)BrF(3)N(2)O(3), has an almost planar conformation, the dihedral angle between the aromatic rings being 3.60 (16)°. The mol-ecule adopts the enol-imine tautomeric form, with an intra-molecular O-H⋯N hydrogen bond, which generates an S(6) ring motif. In the crystal, face-to-face π-π stacking [centroid-centroid distances = 3.669 ...

In the title compound, C(13)H(8)ClN(3)O(3)·C(3)H(7)NO, the benzimidazole and benzene rings make a dihedral angle of 0.63 (11)°. An intra-molecular O-H⋯N hydrogen bond generates an S(6) ring motif. The solvent mol-ecule is hydrogen-bonded to the benzimidazole mol-ecule by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds, generating an R(1) (2)(7) ring motif. In the crystal, the mol-ecules are arra...

In the title compound, C20H16N2O4, the mol-ecule adopts an E conformation about the N=C bond. There is an intra-molecular O-H⋯N hydrogen bond forming an S(6) ring motif. The nitro-benzene and benz-yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively, and to one another by 31.40 (12)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds, form...

The title Schiff base compound, 4-nitro-1-oxo-2-{(E)-[2-(piperidin-1-yl)ethyl]iminiomethyl}cyclohexadienide, C(14)H(19)N(3)O(3), exists as a zwitterion, with the H atom of the phenol group being transferred to the imine N atom. The C=O, C(Ar)-C(Ar) and C-N bond lengths are in agreement with the oxocyclohexadienide-iminium zwitterionic form. The iminium H atom is engaged in a strong intramolecul...

A new unsymmetric thioether diamine N - ( 2 - ( 2 - aminophenylthio) ethyl) benzene - 1 , 2 - diamine was prepared through the nucleophilic substitution of cysteaminium chloride with 1 - chloro - 2 - nitrobenzene and then the nitro groups of prepared compuond converted to the amine by zinc powder and ammonium chloride. Then, unsymmetric Schiff bass ligand 2 - ((( 2 - (( 2 - (( 2 - (( 2 - hydrox...

In this study, the catalytic use of [Pd(L1)2]Cl2 complex is aimed for reduction / degradation reactions organic pollutants in water sources which pose a threat to environment. For purpose, 2-(thiophen-2-yl)-1H-benzimidazole ligand (L1) and its Pd(II) (C1) were synthesized characterized by FT-IR, 1H-NMR, 13C-NMR, ESI-MS spectroscopic techniques. The efficiency C1 on 4-nitro phenol compound (4-NP...