We examined the synthesis and characterization of polymer micelle using polymerizable cationic gemini surfactant (surfmer). Here, cationic gemini surfmer (GS) was newly synthesized and characterized. Also, a “monomer”-type surfmer (MS) was synthesized and characterized for comparison. The equilibrium properties in water and in the presence of 0.1 M NaBr were investigated by means of surface ten...

in this study, preparation of nano-sized gamma alumina with high specific surface area and high yield by thereaction between aluminum nitrate and sodium carbonate, without using any surfactant is reported. bohemite (aluminum oxyhydroxide) was prepared as a precursor by strict control of ph and reaction temperature. the gel produced was purified by washing followed by centrifugation. the specifi...

nanoparticles of coordination polymer [co2(pydc)2(h2o)6]n.2n h2o [h2pydc = pyridine-2,5-dicarboxylic acid] have been synthesized by sonochemical method and characterized by elemental analysis, infrared spectroscopy, powder x-ray diffraction, scanning electron microscopy, dls particle size analysis and tga/dta. the structure of single crystalline coordination polymer developed from nanosized coo...

Magnesium-ion conducting gel polymer electrolytes (GPEs) with different contents of nano-sized MgO have been prepared and investigated by various electrical and electrochemical techniques. The Mg2+ ion conduction in GPEs was confirmed from cyclic voltammetry and impedance analysis. It was found that doping appropriate nano-sized MgO in the GPE can induce significant improvements in both the ele...

Nano-sized TiCx/2009Al composites (with 5, 7, and 9 vol% TiCx) were fabricated via the combustion synthesis of the 2009Al-Ti-CNTs system combined with vacuum hot pressing followed by hot extrusion. In the present study, CNTs were used as the carbon source to synthesize nano-sized TiCx particles. An attempt was made to correlate the effect of ground CNTs by milling and the distribution of synthe...

We report on the collapsing and reswelling ability of grafted poly(methyl vinyl ether) chains of different molecular architectures. In order to study the influence of constraints and confinement of the chains, the polymer was grafted onto AFM tips, as a model of a curved nano-sized surface, and onto macroscopic silicon substrates for comparison purposes. AFM-based force spectroscopy experiments...

In current study, nanoparticles and single crystals of a Zn(II) coordination complex, [Zn(dmph)I2](1), {dmph=2,9-dimethyl-1,10-phenanthroline(neocuproine)}, have been synthesized by the reaction of zinc(II) acetate, KI and neocuproine as ligand in methanol using sonochemical and heat gradient methods, respectively. The nanostructure of 1 was characte...

Supported olefin polymerization catalysts can prevent reactor-fouling problems and produce uniform polymer particles. Constrained geometry complexes (CGCs) have less sterically hindered active sites than bis-cyclopentadienyl metallocene catalysts. In the literature, micrometer-sized silica particles were used for supporting CGC catalysts, which might have strong mass transfer limitations. This ...