Iron(III) oxide shows a polymorphism, characteristic of existence of phases with the same chemical composition but distinct crystal structures and, hence, physical properties. Four crystalline phases of iron(III) oxide have previously been identified: α-Fe2O3 (hematite), β-Fe2O3, γ-Fe2O3 (maghemite), and ε-Fe2O3. All four iron(III) oxide phases easily undergo various phase transformations in re...

The effect of Fe2O3 crystal phases on their performance in CO2 hydrogenation was studied. α-Fe2O3 crystal was prepared by precipitation method from Fe(NO3)3·9H2O and (NH4)2CO3, and γ-Fe2O3 was prepared by grinding Fe(NO3)3·9H2O and L(+)-Tartaric acid in agate mortar completely. The crystal phases of Fe2O3 influence the distribution of promoter Zn, K and Cu on catalysts. The dispersity of K on γ...

The atomic structure and properties of nanoparticulate Fe2O3 are characterized starting from its smallest Fe2O3 building unit through (Fe2O3)n clusters to nanometer-sized Fe2O3 particles. This is achieved by combining global structure optimizations at the density functional theory level, molecular dynamics simulations by employing tailored, ab initio parameterized interatomic potential function...

Cobalt ferrite nano-powder have been obtained through a hydrothermal method with 2:1 molar ratio of Fe:Co without using any surfactant. X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) were used to consider the structural and morphological properties of CoFe2O4 nano-particles. Also, EDAX spectroscopy applied to evaluate the chemical composition. Results demonstrated that 15 hr hyd...

Fe2O3 nanorods exposing (001) and (010) plane as well as Fe2O3 nanosheets exposing (001) plane have been successfully synthesized. Fe2O3 nanosheets exhibit better cycle performance and rate capabilities than that of Fe2O3 nanorods. The discharge capacity of Fe2O3 nanosheets can stabilize at 865 mAh/g at the rate of 0.2 C (1C = 1000 mA/g) and 570 mAh/g at the rate of 1.2 C after 80 cycles, which...

The effect of TiO2 layer applied to the conventional Fe2O3/FTO photoanode to improve the photoelectrochemical performance was assessed from the viewpoint of the microstructure and energy band structure. Regardless of the location of the TiO2 layer in the photoanodes, that is, Fe2O3/TiO2/FTO or TiO2/Fe2O3/FTO, high performance was obtained when α-Fe2O3 and H-TiNT/anatase-TiO2 phases existed in t...

Marine concrete structures are subject to the action of multiple environments during their service time. This leads increased deterioration in durability marine concretes under combined bending load and dry–wet cycles, salt freeze–thaw spray erosion. The main reason for damage above three is Cl- attack. free content (Cl-f) diffusion coefficient (Df) can explain concrete. paper considers actual ...

A nano-hollow zeolite-encapsulating ultra-fine Fe nanoparticle catalyst denoted as Fe@n-hS-HT was successfully synthesized through a simple water steam treatment of the Fe@n-hS prepared by “dissolution–recrystallization” (D-R) method. The had hierarchical porous structure and high dispersion Fe2O3 particles with size 3.4 nm. Furthermore, results several characterization methods, such XRD, HAADF...

Nanoparticles (NPs) of lead tetroxide (Pb3O4) with the spherical morphology were manufactured by reaction nitrate sodium hydroxide, while nanoparticles red iron oxide (Fe2O3) similar fabricated hydrothermal route in presence ferric chloride hexahydrate as precursor. Evaluation chemical structure, purity and Fe2O3 Pb3O4 NPs was carried out analysis via X-ray diffraction (XRD) well scanning elect...