نتایج جستجو برای: molybdate sulfuric acid
تعداد نتایج: 749084 فیلتر نتایج به سال:
Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosol nucleation. Based on quantum chemical calculations it has been suggested that the quantitative detection of gas phase sulfuric acid (H2SO4) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased in the presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campai...
The range of inorganic acid normalities for maximum color formation of the phosphomolybdenum-blue complex (under heating) increases by elevating the ammonium molybdate concentra tion, and at a ratio of molybdate molarity/acid normality equal to 10, there is maximum color development at any acid normality in the range 1—4 n with either HC104 or H2S04 (or their mixtures). On the basis of these f...
A 1,10-phenanthroline (phen) chelated molybdenum(VI) citrate, [(MoO2)2O(H2cit)(phen)(H2O)2] x H2O (1) (H4cit = citric acid), is isolated from the reaction of citric acid, ammonium molybdate and phen in acidic media (pH 0.5-1.0). A citrato oxomolybdenum(V) complex, [(MoO)2O(H2cit)2(bpy)2] x 4H2O (2), is synthesized by the reduction of citrato molybdate with hydrazine hydrochloride in the presenc...
In microaerophilic or anaerobic environments, Pseudomonas aeruginosa utilizes nitrate reduction for energy production, a process dependent on the availability of the oxyanionic form of molybdenum, molybdate (MoO4 (2-)). Here, we show that molybdate acquisition in P. aeruginosa occurs via a high-affinity ATP-binding cassette permease (ModABC). ModA is a cluster D-III solute binding protein capab...
Formaldehyde in small quantities is commonly analyzed by spectrophotometric methods. One of the most-commonly used spectrophotometric techniques for this purpose is based on the reaction with chromotropic acid. Because of its simplicity, sensitivity, selectivity and its low cost, it is still widely used. Investigations for replacing the concentrated sulfuric acid with other acids or using more ...
The atmosphere is an inhomogeneous system of vapors, and liquid as well as solid particles. The nucleation process is an important source of particles, observed at most sites where particle measurements have been carried out. Sulfuric acid plays an important role in the first steps of particle formation, but a complete picture of process, after several years of research, is still unclear. Compu...
Neat chlorosulfonic acid reacts with anhydrous sodium tungstate to give tungstate sulfuric acid (TSA), a new dibasic inorganic solid acid in which two sulfuric acid molecules connect to a tungstate moiety via a covalent bond. A variety of oximes were oxidized to their parent carbonyl compounds under mild conditions with excellent yields in short times by a heterogeneous wet TSA/KMnO4 in dichlor...
In this paper we develop a policy model for pollution control investment and operational decisions in the copper industry. The system consists of (i) a nonlinear integer model to optimize smelter operations, including the investment decisions relating to smelting capacity and pollution control plants that complies with environmental regulations, and (ii) a network flow model to describe the eco...
The effect of specimen aging on the recovery of mercury from urine samples was investigated. It was found that in some aged specimens the addition of concentrated sulfuric acid to the urine without cooling resulted in a large loss of mercury. This phenomenon is presumed to be due to enhanced volatility of the mercury caused by bacterial action. This loss can be avoided by adding a suitable pres...
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