in this paper, we report the synthesis and characterization of a new symmetric macroacyclic schiff base ligand (h2l) and related complexes with different metals. (h2l) was synthesized by the one pot condensation reaction of 2-[2-(2-formyl phenoxy)ethoxy]benzaldehyde and 2-aminobenzenethiol in a 1:2 molar ratio. the acyclic schiff base was characterized by ir, nmr spectroscopy and elemental anal...

The effects of cAMP-analogue dibutyryl-cAMP and anticalmodulin W-7 were studied on de novo synthesis and secretion of lipids in cultures of hepatoma McArdle RH7777 cells and normal rat hepatocytes. Dibutyryl-cAMP and W -7 separately caused a significant decrease in the secretion of de novo synthesized triacyl [3H]glycerol in both cultures of McArdle cells and rat hepatocytes. The inhibito...

The acoustical parameters of some synthesized azomethines have been studied from ultrasonic velocity and density measurement at different concentration in methanol and dimethyl formamide at 303.15 K. The apparent adiabatic molar compressibilities and apparent molar volume were also evaluated. The results provide useful information about solute-solute and solute-solvent interactions and are of s...

objective: the present study assessed the association of size, axial angulation, developmental stage and bud position of the mandibular third molar with the second molar impaction in patients with mandibular second molar impaction. methods: in this descriptive-analytical study (case-control design), dental records of 5,420 patients in the age range of 12-15 years who underwent orthodontic treat...

It has been demonstrated that healthy centenarians have more favorable anthropometric characteristics and insulin-mediated glucose uptake than aged subjects. The plasma insulin-like-growth factor I (IGF-I) concentration may account for such differences. Three groups of subjects were studied: 1) adults (< 50 yr; n = 30), 2) aged subjects (75-99 yr; n = 30), 3) centenarians (> 100 yr; n = 19). In...

Dielectric relaxation of different molar concentrations of ethanol (C2H5OH) in binary mixtures of ethanol and chlorobenzene in benzene solutions has been studied at 9.883 GHz by using standard standing microwave techniques and Gopala Krishna’s single frequency concentration variation method at different temperatures (25 ◦C, 30 ◦C, 35 ◦C, and 40 ◦C). It was found that the dielectric relaxation t...

The production of lactic acid from glycerol by means of the alkaline hydrothermal process was evaluated using high concentrations of glycerol. The operating conditions that influence the hydrothermal process were studied. Temperature (250 280 °C), catalyst to glycerol molar ratio (0.05 to 0.15), and water to glycerol volumetric ratio (0.8 to 1.5) were evaluated, as well as the use of NaOH and K...

positive partial molar adiabatic compressibilities of transfer at infinite dilution, ∆tr o s 2 , κ , have been observed for the studied amino acids (except at lower concentration up to ≈ 0.6 mB in some cases), and their magnitude increases with increase in concentration of glycerol. B-coefficient of transfer, ∆trB, values are positive for these amino acids, which after passing through maxima ≈3...

From measurements of the surface tension, density, viscosity and light scattering of aqueous solutions of methanol, ethanol and propanol at 293 K, their activity in the surface monolayer, surface excess concentration, and apparent and partial molar volume were determined. The surface excess concentration of alcohols at the water-air interface was determined from the Gibbs equation by using both...

Near real time process monitoring of the uranium content in an aqueous fuel recycling plant is a desired component of an advanced safeguards suite; Ultraviolet– Visible spectroscopy and Time Resolved Laser induced Fluorescence Spectroscopy can contribute to this technology gap. This work presents the observation of the spectroscopic parameters (molar absorptivities, fluorescent response) of the...