نتایج جستجو برای: mof 199

تعداد نتایج: 13180  

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه صنعتی شیراز - دانشکده مهندسی شیمی 1392

اتیلن یکی از مهمترین محصولات پتروشیمی می باشد که در واحد الفین تولید می گردد و به عنوان خوراک در واحدهای پلیمری مصرف می شود. چالش برانگیزترین مرحله در خالص سازی اتیلن در واحدهای الفین، حذف استیلن می باشد که حضور کمترین مقدار آن باعث مسمومیت کاتالیست های پلیمریزاسیون اتیلن و در نتیجه کاهش کیفیت پلی اتیلن تولیدی می شود. در این تحقیق روش جداسازی غشایی با استفاده از معادله حالت phsc برای جداسازی اس...

2013
Richard L. Martin Li-Chiang Lin Kuldeep Jariwala Berend Smit Maciej Haranczyk

Metal−organic frameworks (MOFs), a class of porous materials, are of particular interest in gas storage and separation applications due largely to their high internal surface areas and tunable structures. MOF-5 is perhaps the archetypal MOF; in particular, many isoreticular analogues of MOF-5 have been synthesized, comprising alternative dicarboxylic acid ligands. In this contribution we introd...

2018
Wei Liu Zhijie Yan Xiaolu Ma Tie Geng Haihong Wu Zhongyue Li

Surface modification on Mg alloys is highly promising for their application in the field of bone repair. In this study, a new metal-organic framework/MgF₂ (Mg-MOF-74/MgF₂) composite coating was prepared on the surface of AZ31B Mg alloy via pre-treatment of hydrofluoric acid and in situ hydrothermal synthesis methods. The surface topography of the composite coating is compact and homogeneous, an...

2017
Thomas P Vaid Steven P Kelley Robin D Rogers

Traditional synthesis of metal-organic frameworks (MOFs) involves the reaction of a metal-containing precursor with an organic linker in an organic solvent at an elevated temperature, in what is termed a 'solvothermal' reaction. More recently, many examples have been reported of MOF synthesis in ionic liquids (ILs), rather than an organic solvent, in 'ionothermal' reactions. The high concentrat...

دهستانی, مریم, زیدآبادی نژاد, لیلا, پوراسترآبادی, صدیقه,

In this study, energy and chemical interaction of ZnO and CdS surfaces interfaced with metal-organic framework (MOF), to improve their properties, have been investigated using density functional theory (DFT). Results show that reformation of structures by hybridation with MOF can increase their stability and improve their properties. Comparison of ZnO and CdS structures predict that deposition ...

2016
Su He Yifeng Chen Zhicheng Zhang Bing Ni Wei He Xun Wang

Metal–organic frameworks (MOFs) usually have micropores smaller than 2 nm, which may restrict their applications in some cases. Hierarchical-pore MOFs (H-MOFs) are a new family of MOF materials, possessing both microand mesopores to address this problem. Here we demonstrate a competitive coordination strategy for the synthesis of H-MOF nanostructures, such as two-dimensional (2D) H-MOF nanoshee...

Journal: :Cell 2008
Jop Kind Juan M. Vaquerizas Philipp Gebhardt Marc Gentzel Nicholas M. Luscombe Paul Bertone Asifa Akhtar

Dosage compensation, mediated by the MSL complex, regulates X-chromosomal gene expression in Drosophila. Here we report that the histone H4 lysine 16 (H4K16) specific histone acetyltransferase MOF displays differential binding behavior depending on whether the target gene is located on the X chromosome versus the autosomes. More specifically, on the male X chromosome, where MSL1 and MSL3 are pr...

2017
Qianqian Li Quan Liu Jing Zhao Yinying Hua Jiajia Sun Jingui Duan Wanqin Jin

In order to promote the selective water permeation through porous filler, hydrophilic MOF-801 crystals with superior water adsorption ability were incorporated into chitosan (CS) matrix to fabricate MOF-801/CS mixed matrix membranes (MMMs) for pervaporation dehydration of ethanol. Both the experimental and molecular simulation results confirm the selective adsorption of water molecules in MOF-8...

2017
Hao Bin Wu Xiong Wen David Lou

In addition to their conventional uses, metal-organic frameworks (MOFs) have recently emerged as an interesting class of functional materials and precursors of inorganic materials for electrochemical energy storage and conversion technologies. This class of MOF-related materials can be broadly categorized into two groups: pristine MOF-based materials and MOF-derived functional materials. Althou...

Journal: :ACS applied materials & interfaces 2012
Lev Bromberg Yaroslav Klichko Emily P Chang Scott Speakman Christine M Straut Eugene Wilusz T Alan Hatton

Aluminum aminoterephthalate MOF particulate materials (NH(2)-MIL-101(Al) and NH(2)-MIL-53(Al)), studied here as components of self-detoxifying surfaces, retained their reactivity following their covalent attachment to protective surfaces utilizing a newly developed strategy in which the MOF particles were deposited on a reactive adhesive composed of polyisobutylene/toluene diisocyanate (PIB/TDI...

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