Aqueous suspensions of exfoliated Li0 .25MoO 3 and Na-montmorillonite have been combined and dried to form interstratified solids. X-ray diffraction patterns of ethylene glycol treated films show that the d-spacing of restacked materials varies with composition between the limits established by the two end members. Based on these data, we conclude that the new materials are composed of individu...

This work evaluated the synergistic effect of citronella essential oil (Ct) and montmorillonite (MMT) (called hybrid compound) incorporated in Poly(lactic acid) (PLA) films at different concentrations (3, 10, 15, 20 wt%). PLA were characterized using X-ray diffraction, SEM, TGA, DSC considering their mechanical properties migration. XRD analysis showed effective interaction between MMT oil. The...

Nanocomposites (NC) were formed using cationic poly(L-lysine) (PLL), a semicrystalline polypeptide, that was reinforced by sodium montmorillonite (MMT) clay via solution intercalation technique. By varying solution conditions such as pH, temperature, and polypeptide concentration in the presence of clay platelets, the secondary structure of PLL was controllably altered into a-helical, b-sheet, ...

Metal chalcogenides based on the C–M–M–C (C = chalcogen, M = metal) structure possess several attractive properties that can be utilized in both electrical and optical devices. We have shown that specular, large area films of γ-InSe and Sb2Se3 can be grown via atomic layer deposition (ALD) at relatively low temperatures. Optical (absorption, Raman), crystalline (X-ray diffraction), and composit...

Partially exfoliated poly (methyl methacrylate) (PMMA) / montmorillonite clay nanocomposite was synthesized via the free radical polymerization of MMA in the presence of alkyl ammonium substituted polysilsesquioxane surfactant-modified clay and AIBN initiator in supercritical CO2. MMT clay was initially cation exchanged with the surfactant to enhance its hydrophobicity and to expand the interla...

The article deals with the preparation, properties and the usage of polymer barrier films. The problem of exfoliation and dispersion of the filler in the polymer matrix and mechanical properties of barrier films is discussed. This problem is connected with the use of nanofiller either in the polymer matrix or on the surface of prepared films. Together the evaluating comparison of used nanofille...

Crystallization of poly(vinyl alcohol) in the presence of an inorganic filler surface (sodium montmorillonite, MMT) was observed and compared to the crystallization of the neat polymer. For this purpose, several atomic force microscopy modes, providing spatial resolution between amorphous and crystalline polymer, are employed to observe filled and unfilled PVA films. The various AFM modes utili...

Thin films prepared via a layer-by-layer (LbL) assembly of renewable materials exhibit exceptional oxygen barrier and flame-retardant properties. Positively charged chitosan (CH), at two different pH levels (pH 3 and pH 6), was paired with anionic montmorillonite (MMT) clay nanoplatelets. Thin-film assemblies prepared with CH at high pH are thicker, because if the low polymer charge density. A ...

WSe2--a layered semiconductor that can be exfoliated into atomically thin two-dimensional sheets--offers promising characteristics for application in solar energy conversion. However, the lack of controllable, cost-effective methods to scalably fabricate homogeneous thin films currently limits practical application. Here we present a technique to prepare controlled thin films of 2D WSe2 from di...