We study chemical reactions with complex mechanisms under two assumptions: (i) intermediates are present in small amounts (this is the quasi-steady-state hypothesis or QSS) and (ii) they are in equilibrium relations with substrates (this is the quasiequilibrium hypothesis or QE). Under these assumptions, we prove the generalized mass action law together with the basic relations between kinetic ...

It follows from equation (1) that when l/u is plotted (usually as the ordinate) against l/s a straight line will be obtained with inhibitory action influencing either the slope or the ordinate intercept or both. Thus the type of inhibition may be defined on the basis of the effect of the inhibitory action upon the slope and intercept in the above plot. In the absence of an inhibitor (i = 0) equ...

Background: The purpose of this study was to evaluate the risk peri-prosthetic fracture constructs made with cephalomedullary (CM) long and short nails. nails were titanium alloy (Ti-6Al-4V) stainless steel (SS 316L). Methods: Biomechanical evaluation CM nail carried out regard post-primary healing determine peri-implant/peri-prosthetic fractures. Therefore, research comprised of, non-fractured...