HMCM-22 with a Si:Al molar ratio of 15:1 has been shown to effectively catalyze the synthesis of acetals with 100% selectivity by the reaction of aldehydes with methanol under reflux conditions. Platelet HMCM-22 particles were prepared by the static strategy and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), BET tech...

Critical to the applications of proteins in non-aqueous enzymatic processes is their structural dynamics relation solvent polarity. A pool mutants derived from Geobacillus zalihae T1 lipase was screened organic solvents (methanol, ethanol, propanol, butanol and pentanol) resulting selection six at initial screening (A83D/K251E, R21C, G35D/S195 N, K84R/R103C/M121I/T272 M R106H/G327S). Site-direc...

It is not sufficiently appreciated that methly alcohol is very toxic. For econoi' reasons, methyl (wood) alcohol is employed as a substitute for tbyl (grain) alcohol, in what may be termed comparatively innocent products, such as perfumes, hair tonics, skin lotions, , '/ polishes, varnishes, etc. Government analysts, not infrequently, find it employed in the manufacture of various extracts for ...

Acute loss of vision and alcoholic intoxication suggests the possibility of methanol poisoning. In this report we describe an alcoholic patient who complained of blindness after recovering from alcoholic pancreatitis and delirium tremens. Visual acuity was severely impaired and fundoscopy revealed florid bilateral cotton wool spots and a cherry red spot at the right macula. Such appearances hav...

A mass spectrometric method has been delineated for the identification of the epoxide functionalities in unknown monofunctional analytes. This method utilizes gas-phase ion/molecule reactions of protonated analytes with neutral trimethyl borate (TMB) followed by collision-activated dissociation (CAD) in an ion trapping mass spectrometer (tested for a Fourier-transform ion cyclotron resonance an...

results escherichia coli phytase was expressed in p. pastoris under different cultivation conditions (post-induction temperature, methanol concentration, and post-induction ph). the optimized conditions by rsm using face centered central composite design were 1% (v/v) methanol, ph = 5.8, and 24.5°c. under the optimized conditions, appa was successfully expressed in p. pastoris and the maximum p...

The desolvation of lattice methanol from between the 1D chains in {[Cu(4,4'-bipyridine)(ccnm)(2)].4MeOH} (ccnm = carbamoylcyanonitrosomethanide) under ambient conditions, a weight loss of 22.4%, results in a solid state conversion to the 3D network [Cu(4,4'-bipyridine)(ccnm)(2)].

Palladium complexes immobilized onto generation 0-3 PAMAM dendrimers supported on silica were used as catalysts for the carbonylation of iodobenzene in methanol to form methyl benzoate. High yields were obtained and the catalyst was recycled 4-5 times without significant loss of activity. The carbonylation reaction was found to be applicable to a variety of iodoarenes regardless of the nature o...

BACKGROUND Methanol poisoning is one of the most important poisoning due to drinking of illegal and non-standard alcoholic beverage in some countries. Relatively limited studies have been carried out to identify the prognostic factors in methanol poisoning. MATERIALS AND METHODS We performed a retrospective study on acute methanol-intoxicated patients, which were admitted on the Loghman Hakim...

the presence of tribolium castaneum (herbst) in a stored food results in contamination and substantial economic damage due to loss of the products and a decrease in nutritional value. this study was conducted to determine the pesticidal and pest repellent activities of roots of laportea crenulata gaud. against t. castaneum. pesticidal activity was determined using surface film method, whereas, ...