In the last decade, significant research efforts were devoted to obtaining materials with welldefined nanostructures for a wide range of applications (Hamley, 2003; Soler-Illia et al., 2002; Paul & Sharma, 2006). Mesoporous silica materials like M41S, HMS, SBAn, FSM, and MSU, among others, are a fairly new type of material that has pores in the mesoscopic range of 2–50 nm (Wan et al., 2007). Th...

Hierarchical MFI zeolite was synthesized following a synthesis route using organic-inorganic hybrid surfactants; the resultant zeolite with mesoporous/microporous hierarchical structure exhibited remarkably high resistance to deactivation in catalytic activity of various reactions such as isomerization of 1,2,4-trimethylbenzene, cumene cracking, and esterification of benzyl alcohol with hexanoi...

Template-derived carbon is demonstrated to effectively promote the creation of strong basicity on mesoporous silica, for the first time. New materials owning ordered mesoporous structure, strong basicity, and excellent catalytic activity are thus successfully constructed at low temperatures, which are impossible to achieve using conventional methods.

Mesoporous alumina and magnesia were prepared using various polymers, poly(ethylene glycol) (PEG), poly(vinyl alcohol) (PVA), poly(N-(2-hydroxypropyl) methacrylamide) (PHPMA), and poly(dimethylacrylamide) (PDMAAm), as porogenic structure matrices. Mesoporous alumina exhibits large Brunauer–Emmett–Teller (BET) surface areas up to 365 m2 g−1, while mesoporous magnesium oxide possesses BET surface...

According to IUPAC nomenclature, mesoporous materials are those materials having a pore size ranging from 2 to 50nm in diameter [1-6]. Mesoporous silica nanoparticles (MSNs) are promising and novel drug vehicles due to their unique mesoporous structure, which preserve a level of chemical stability, surface functionality and biocompatibility and ensure controlled release and targeted delivery of...

Noble Gemini surfactants containing a siloxane moiety have been designed and successfully synthesized in the present study and are utilized as structure-directing agents for mesoporous metal oxides such as zirconia, titania, and vanadia. The siloxane moiety is believed to play an important nano-propping role during the surfactant removal by direct calcination, yielding thermally stable mesoporo...

the recognition of the biologically and environmentally important ions is of great interest in the field of chemical sensors in recent years. the fluorescent sensors as a powerful optical analytical technique for the detection of low level of various analytes such as anions and metal cations have been progressively developed due to the simplicity, cost effective, and selectivity for monitoring ...

We fabricated a series of mesoporous silicas and mesoporous organosilicates with hierarchical porosity through evaporation-induced self-assembly using Pluronic F127 as a template in this study. We could tailor the mesophase of each mesoporous silica sample by varying the weight ratio of its two silica sources: tetraethyl orthosilicate (TEOS) and triethoxysilane hydrosilylated octavinyl polyhedr...

A hierarchical excavated iron-nitrogen codoped mesoporous carbon (Ex-FeN-MC) electrocatalyst has been successfully synthesized by pyrolysis of the unique ureidopyrimidinone containing organic precursor MAMIS by using silica as the mesoporous template and iron nitrate as the source of iron. The selected organic precursor has multifunctionalities with diverse distribution of nitrogen and oxygen s...

Drug molecules with lack of specificity and solubility lead patients to take high doses of the drug to achieve sufficient therapeutic effects. This is a leading cause of adverse drug reactions, particularly for drugs with narrow therapeutic window or cytotoxic chemotherapeutics. To address these problems, there are various functional biocompatible drug carriers available in the market, which ca...