A comprehensive mechanistic study conducted on the formation mechanism of five-fold twinned copper nanowires by heating copper(I) chloride with oleylamine at 170 °C is presented. Electron microscopy and UV-visible absorption spectra are used to analyze the growth mechanism of copper nanowires. High-resolution transmission electron microscopy and selected-area electron diffraction are used to in...

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Investigations of voltammetry zirconium deposition from DMSO solution on different substrates were taken. It was found that this is multi-electron process proceeding in a few stages. Moreover, zirconium layers were obtained on titanium, copper stainless steel and nickel. Obtained deposit was in form of white powder, which immediately was oxidized to ZrO2 in the presence of air.

An ultralow amount of platinum can be deposited on the gold surface using copper underpotential deposition and galvanic exchange. The platinum tended to deposit as layers on the octahedral gold nanocrystals with an Au(111) surface, while it aggregated and formed small particles on the cubic gold nanocrystals with an Au(100) surface.

Copper on gold forms a monolayer deposit via underpotential deposition. For gold particles adsorbed at a liquid-liquid interface this results in a uniform one monolayer thick shell. This approach offers a new route for the uniform functionalisation of nanoparticles and presents a way to probe fundamental processes that underlie nanoparticle synthesis.

The feasibility of processing low-grade copper-nickel ores by heap bioleaching was investigated. It found that an iron-oxidizing strain acidophilic microorganisms, Acidithiobacillus ferrivorans, is effective in the leaching sulfide from deposits Russia’s Murmansk region. Sulfide mineralization studied mineral feeds described using methods X-ray phase analysis and optical microscopy. In process ...

Abstract Detailed mineralogical and textural studies, combined with sequential X-ray diffraction geochemical modeling, helped to solve the “copper pitch/wad” enigma in Exótica deposit located downstream of Chuquicamata porphyry copper deposit. Copper pitch wad are essentially chrysocolla co-precipitated Mn oxides, mainly birnessite, as well pseudo-amorphous oxide/oxyhydroxides. Linking mineralo...