An N-fused BDOPV derivative, NBDOPV, was designed and synthesized. The photophysical and electrochemical properties of NBDOPV were systematically investigated. The NBDOPV-based conjugated polymer PITET shows a large hole mobility of 1.92 cm(2) V(-1) s(-1).

Sphagesaurus montealtensis is a sphagesaurid whose original description was based on a comparison with Sphagesaurus huenei, the only species of the clade described to that date. Better preparation of the holotype and the discovery of a new specimen have allowed the review of some characteristics and the identification of several synapomorphies of S. montealtensis with the genus Caipirasuchus: p...

The highly enantioselective synthesis of densely functionalized 2,3-indoline-cyclobutanes by means of chiral gold catalysis is presented. Intermolecular formal [2+2]-cycloaddition reactions between substituted indoles and allenamides enabled direct access to methylenecyclobutane-fused indolines, featuring two consecutive quaternary stereogenic centers with excellent stereochemical control (dr >...

Landmark-based high-dimensional diffeomorphic maps of the hippocampus (although accurate) is highly-dependent on rater's anatomic knowledge of the hippocampus in the magnetic resonance images. It is therefore vulnerable to rater drift and errors if substantial amount of effort is not spent on quality assurance, training, and re-training. A fully-automated, FreeSurfer-initialized large-deformati...

An efficient method towards the synthesis of quinoline fused tricyclic compounds involving an intramolecular 1,3-dipolar nitrile oxide cycloaddition reaction utilizing Baylis-Hillman derivatives in good yields has been described for the first time. A highly functionalized tricyclic framework was created by forming two rings and two adjacent stereocentres through the formation of two N-C bonds, ...

The term Riga-Fede disease has been used to describe chronic traumatic ulceration that occurs on the ventral surface of the tongue by natal and neonatal teeth in infants. It is important to diagnose the lesion and treat it by eliminating the source of trauma. In this case report, the neonatal tooth was extracted and after 2 weeks the lesion was resolved and the baby was feeding well.In addition...

intraosseous movement of an unerupted tooth across the midline of the jaw is known as dental transmigration. this infrequent event is mostly found in the mandibular canines. there are four new cases of mandibular canine transmigration presented here. the literature on this anomalous phenomenon is also reviewed.

introduction multiple dentigerous cysts are rare and mostly associated with syndromes. case presentation the present case report is unique, as the dentigerous cysts enclosed the lateral incisor, canine, first and second premolars of the mandible and were accompanied by a complex odontoma, instead of first mandibular molar. conclusions multiple unilateral nosyndromic dentigerous cysts with compl...

this report presents a rare case of bi-rooted primary maxillary canines. a 6-year-old girl presented at the department of pediatric dentistry, faculty of dentistry, mashhad university of medical sciences, iran, with the chief complaint of pain in the lower right quadrant of her dentition. radiographic examination revealed bifurcation of primary maxillary canine roots. this report discusses the ...