in this research, chitosan was used for the removal of cr (vi) ions from aqueous solution. the effect of parameters like solution ph, initial cr (vi) concentration, agitation time, amount of adsorbent and agitation speed on the adsorption process was studied. the experimental equilibrium data were analyzed by using various models such as langmuir and freundlich. freundlich isotherm model fitted...

In this paper we used a previously reported model for examining the adsorption of nonelectrolytes in solution by solid adsorbents to study the adsorption of lithium(I) cations by acid and sodium amberlites, which is an ion-exchange process. Based on the results, both are equilibrium processes and obey a kinetic law with a unity partial order in the Li+ concentration. The kinetic results were us...

Models for the gating of ion channels usually assume that the rate constants for leaving any given kinetic state are independent of previous channel activity. Although such discrete Markov models have been successful in describing channel gating, there is little direct evidence for the Markov assumption of time-invariant rate constants for constant conditions. This paper tests the Markov assump...

Conventional measurements of kinetic constants currently in use are performed at equilibrium and may require large volumes, especially a low association rate constant kon. If the made out equilibrium, values obtained be biased by dilution sample with flow running buffer. In some applications, available volume can very critical requires development tools to measure volumes. this paper, combining...

Herein a quenched-flow kinetic technique was applied to calculate the rate constants of 1-hexene and 1-octene oligomerization catalyzed by the Cp2ZrCl2 and Cp2HfCl2/MAO catalyst systems, and subsequently a mechanism for the higher α-olefin oligomerization reaction was proposed. The oligomerization results showed that Zr-based catalyst in the oligomerization of 1-octene had the highest activity ...

The optimization of process conditions for the degradation of Acid Blue 193 by UV/peroxydisulfate was investigated using response surface methodology (RSM). The effects of four parameters namely initial K2S2O8 concentration, UV irradiation, temperature, and initial dye concentration on two process responses, color removal and the rate constants of the first-order kinetic equations, were investi...

Batch kinetic experiments were carried out for the sorption of methylene blue onto activated carbon. The experimental kinetics were fitted to the pseudo first-order and pseudo second-order kinetics by linear and a non-linear method. The five different types of Ho pseudo second-order expression have been discussed. A comparison of linear least-squares method and a trial and error non-linear meth...