A simple and precise incremental isoconversional integral method based on Li-Tang (LT) method is proposed for kinetic analysis of solid thermal decomposition, in order to evaluate the activation energy as a function of conversion degree. The new method overcomes the limitation of LT method in which the calculated activation energy is influenced by the lower limit of integration. By applying the...

Degradation kinetics of organic-inorganic hybrid materials based on epoxy resin was investigated by thermogravimetric analysis (TGA). The hybrid materials were prepared from diglycidyl ether of bisphenol A (DGEBA) and 3-glycidyloxypropyltrimethoxysilane (GLYMO) polymerised simultaneously by poly(oxypropylene)diamine (Jeffamine D230). Nanometric level of homogeneity in the hybrids was verified b...

The kinetics of mercury removal from solid wastes generated by chlor-alkali plants were studied. The reaction order and model-free method with an isoconversional approach were used to estimate the kinetic parameters and reaction mechanism that apply to the thermal decomposition of hazardous mercury wastes. As a first approach to the understanding of thermal decomposition for this type of system...

D. Wang, S. Zhang, Q. Wang. School of Materials and Metallurgy, University of Science and Technology Liaoning, China Z. Zhao. School of Chemistry and Life Science, Anshan Normal University, Liaoning, China G.L. Tan. Department of Chemical Engineering, Yingkou Institute of Technology, Liaoning, China This paper focuses on investigating the decomposition mechanism of ca lcium carbonate. The non-i...